ChemicalBook >>4'-Aminoacetanilide>>N-Acetyl-p-phenylenediamine(122-80-5)

N-Acetyl-p-phenylenediamine(122-80-5)

N-Acetyl-p-phenylenediamine(122-80-5)
Product IdentificationBack to Contents
【Product Name】

N-Acetyl-p-phenylenediamine
【Synonyms】

1-Amino-4-(acetylamino)benzene
4-(Acetylamino)aniline
Butyl a-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate
C.I. 76005
Fourrine A
Fusilade
Halokon
Onecide
Oxidation Base 19
Paracetamin
Propanoic acid, 2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-, butyl ester
【CAS】

122-80-5
【CAS】

69806-50-4
【Formula】

C19H20F3NO4
【Formula】

C8H10N2O
【Molecular Weight】

150.18
【Molecular Weight】

383.37
【EINECS】

204-576-6
【EINECS】

274-125-6
【RTECS】

AD8225000
【RTECS】

UA3000000
【RTECS Class】

Agricultural Chemical and Pesticide; Reproductive Effector; Primary Irritant
【RTECS Class】

Mutagen; Primary Irritant
【Merck】

12,4152
【Merck】

13,410
【Beilstein/Gmelin】

1510062
【Beilstein/Gmelin】

742888
【Beilstein Reference】

4-13-00-00137
【EC Index Number】

607-304-00-8
【EC Class】

irritant
【EC Class】

Toxic for reproduction Category 2; Dangerous for the Environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

A pale straw colored liquid. Selective herbicide.
【Appearance】

White or slightly reddish solid.
【Solubility in water】

Soluble
【Solubility in water】

1 mg/L (20 C)
【Melting Point】

13
【Melting Point】

165
【Boiling Point】

267
【Boiling Point】

436
【Vapor Pressure】

8E-8 (25 C)
【Vapor Pressure】

0.01 (25 C)
【Density】

1.21 g/cm3 (20 C)
【Density】

1.27 g/cm3
【pKa/pKb】

13.22 (pKb)
【pKa/pKb】

9.43 (pKb)
【Partition Coefficient】

5.28
【Partition Coefficient】

.08
【Heat Of Vaporization】

50.6 kJ/mol
【Heat Of Vaporization】

69.2
【Usage】

Herbicide.
【Usage】

Intermediate in the manufacture of azo dyes, pharmaceuticals.
【Refractive Index】

1.52
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Ingestion】

Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
【Inhalation】

If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
【Inhalation】

Irritation of the nose and throat. Repeated exposure can result in liver and kidney damage and depress of the central nervous system.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

May cause irritation. Prolong/repeated exposure may cause dermatitis.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
【Skin】

Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
【Eyes】

May cause irritation.
【Eyes】

If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store under an inert atmosphere.
【Storage】

Keep in a cool, dry location with ventilation and away from incompatible materials. Keep container tightly closed.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air.
【Handling】

Electrically ground all equipment when handling. Do not use pressure to empty containers. Do not get in eyes, on skin or on clothing.
Hazards IdentificationBack to Contents
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Inhalation】

May cause respiratory tract irritation.
【Skin】

May cause skin irritation.
【Eyes】

Causes eye irritation.
【EC Risk Phrase】

R 36/38 42/43
【EC Safety Phrase】

S 22 26 36/37 45
【UN (DOT)】

3335
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Personal Protection】

Protective clothing, PVC gloves when spraying fusilade 4e. Also, apron and full face shield when handling or mixing concentrate.
【Respirators】

NIOSH approved respirator for emission. May be a full face plate, half mask air purifying cartidge respirator for organic vapors and mists or a SCBA in pressure demand mode, supplied air respirator.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Poison Class】

5
Fire Fighting MeasuresBack to Contents
【Flash Point】

195
【Flash Point】

218
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
【Lower exp. limit】

1.1
【Fire Potential】

This material is probably combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Place under an inert atmosphere.
【Small spills/leaks】

Wear protective equipment. For small spills, mop up and place in an approved waste container. For larger spils, dike and then pump into an approved container.
Stability and ReactivityBack to Contents
【Disposal Code】

3
【Incompatibilities】

Air.
【Stability】

Stable for 3 yr at 25 C and for 6 months at 37 C. Reasonably stable in acidic and neutral conditions, but rapidly hydrolyzed in alkaline media (ph 9). Tested stable in storages 40-120 F (5-50 C).
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Oxides of carbon and nitrogen, ammonia.
Transport InformationBack to Contents
【UN Number】

3335
【HS Code】

2924 29 95
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