ChemicalBook >>2-Bromotoluene>>2-Methylbromobenzene(95-46-5)

2-Methylbromobenzene(95-46-5)

2-Methylbromobenzene(95-46-5)
Product IdentificationBack to Contents
【Product Name】

2-Methylbromobenzene
【Synonyms】

1-Bromo-2-methylbenzene
2-Methylbromobenzene
A13-26648
o-Bromotoluene
o-Methylphenyl bromide
o-Tolyl bromide
【CAS】

95-46-5
【Formula】

C7H7Br
【Molecular Weight】

171.04
【EINECS】

202-421-7
【RTECS】

XS7965500
【RTECS Class】

Other
【Merck】

13,1424
【Beilstein/Gmelin】

1904176
【Beilstein Reference】

4-05-00-00825
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear colorless to pale beige liquid.
【Solubility in water】

Insoluble
【Melting Point】

-27
【Boiling Point】

181.5
【Vapor Pressure】

1.2 (25 C)
【Density】

1.4192 g/cm3
【Partition Coefficient】

3.5
【Heat Of Vaporization】

40.0 kJ/mol
【Usage】

Research chemical.
【Vapor Density】

5.9
【Refractive Index】

1.5565 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation. Exposure produces central nervous system depression. May cause kidney damage.
【Skin】

Causes skin irritation.
【Eyes】

Causes eye irritation.
【Ingestion】

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 22 36/37/38
【EC Safety Phrase】

S 26 36/37/39
【UN (DOT)】

1760
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause kidney damage.
【Poison Class】

1 (Extremely strong toxins)
Fire Fighting MeasuresBack to Contents
【Flash Point】

79
【Autoignition】

> 100
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

This chemical is combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

2
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1760
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2903 69 90
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