ChemicalBook >>2-Methyltetrahydrofuran>>Tetrahydro-2-methylfuran(96-47-9)

Tetrahydro-2-methylfuran(96-47-9)

Tetrahydro-2-methylfuran(96-47-9)
Product IdentificationBack to Contents
【Product Name】

Tetrahydro-2-methylfuran
【Synonyms】

2-Methyl tetrahydrofuran
2-Methyloxolane
Tetrahydro-2-methylfuran
Tetrahydrosylvan
【CAS】

96-47-9
【Formula】

C5H10O
【Molecular Weight】

86.13
【EINECS】

202-507-4
【RTECS】

LU2800000
【RTECS Class】

Primary Irritant
【Beilstein/Gmelin】

102448
【Beilstein Reference】

5-17-01-00017
【EC Class】

highly flammable, irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

150 g/L (25 C)
【Melting Point】

-136
【Boiling Point】

79
【Vapor Pressure】

30
【Density】

0.8748 g/cm3 (0 C)
【Partition Coefficient】

.72
【Refractive Index】

1.409 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】

Wash thoroughly after handling. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause digestive tract disturbances.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 10 11 19 36/37
【EC Safety Phrase】

S 9 16 23 33 30
【UN (DOT)】

2536
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

The toxological properties of this substance have not been fully investigated.
Fire Fighting MeasuresBack to Contents
【Flash Point】

-11
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Extremely flammable liquid. Containers may explode in the heat of a fire. Will be easily ignited by heat, sparks or flame. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
【Upper exp. limit】

5.7
【Lower exp. limit】

1.2
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Incompatibilities】

Oxidizing agents, strong acids, strong bases.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2536
【Hazard Class】

3
【Packing Group】

II
【HS Code】

2932 19 00
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