ChemicalBook >>2-Thiophenemethanol>>Thiophene-2-methanol(636-72-6)

Thiophene-2-methanol(636-72-6)

Thiophene-2-methanol(636-72-6)
Product IdentificationBack to Contents
【Product Name】

Thiophene-2-methanol
【Synonyms】

(Thiophen-2-yl)methanol
2-(Hydroxymethyl)thiophene
2-Thenyl alcohol
2-Thienylcarbinol
2-Thienylmethanol
2-Thienylmethyl alcohol
4-Methyl-3-oxo-pentanoic acid ethyl ester
Ethyl 3-oxo-4-methylpentanoate
Ethyl 3-oxo-4-methylvalerate
Ethyl 4-methyl-3-oxopentanoate
Pentanoic acid, 4-methyl-3-oxo-, ethyl ester
Valeric acid, 4-methyl-3-oxo-, ethyl ester
【CAS】

636-72-6
【CAS】

7152-15-0
【Formula】

C5H6OS
【Formula】

C8H14O3
【Molecular Weight】

114.17
【Molecular Weight】

158.19
【EINECS】

211-264-3
【EINECS】

230-491-9
【Beilstein/Gmelin】

383595
【Beilstein/Gmelin】

636726
【Beilstein Reference】

4-03-00-01589
【Beilstein Reference】

5-17-03-00358
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

Slightly soluble
【Solubility in water】

Soluble
【Melting Point】

-9
【Melting Point】

0
【Boiling Point】

173
【Boiling Point】

207
【Vapor Pressure】

0.14 (25 C)
【Density】

1.002 g/cm3 (0 C)
【Density】

1.2147 g/cm3 (14.5 C)
【pKa/pKb】

10.61 (pKa)
【pKa/pKb】

13.88 (pKa)
【Partition Coefficient】

.71
【Heat Of Vaporization】

46.9 kJ/mol
【Vapor Density】

3.94
【Refractive Index】

1.250 (20 C)
【Refractive Index】

1.5280 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

May cause respiratory tract irritation.
【Skin】

May cause skin irritation.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

May cause eye irritation.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

May cause irritation of the digestive tract.
【Ingestion】

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 10
【EC Safety Phrase】

S 23 24/25
【EC Safety Phrase】

S 24/25
【UN (DOT)】

1993
【UN (DOT)】

3334
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Fire Fighting MeasuresBack to Contents
【Flash Point】

53
【Flash Point】

77
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Cover with sand, dry lime or soda ash and place in a closed container for disposal. Provide ventilation.
【Small spills/leaks】

Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Provide ventilation.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Carbon monoxide, oxides of sulfur, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1993
【UN Number】

3334
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2934 99 90
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