ChemicalBook >>Chlorodiphenylmethane>>1,1'-(Chloromethylene)bisbenzene(90-99-3)

1,1'-(Chloromethylene)bisbenzene(90-99-3)

1,1'-(Chloromethylene)bisbenzene(90-99-3)
Product IdentificationBack to Contents
【Product Name】

1,1'-(Chloromethylene)bisbenzene
【Synonyms】

(Chloro-phenylmethyl)benzene
1,1'-(Chloromethylene)bisbenzene
Benzhydryl chloride
Diphenylmethyl chloride
【CAS】

90-99-3
【Formula】

C13H11Cl
【Molecular Weight】

202.69
【EINECS】

202-031-7
【Beilstein/Gmelin】

607925
【Beilstein Reference】

4-05-00-01847
【EC Class】

corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

Insoluble
【Melting Point】

12 - 14
【Boiling Point】

315
【Vapor Pressure】

0.001 (25 C)
【Density】

1.1346 g/cm3 (20C)
【Partition Coefficient】

2.56
【Heat Of Vaporization】

53.5 kJ/mol
【Heat Of Combustion】

-6771 kJ/mol
【Vapor Density】

6.98
【Refractive Index】

1.5951 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
【Handling】

Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Wash clothing before reuse. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. Can produce delayed pulmonary edema.
【Skin】

May cause severe irritation and possible burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Contact with eyes may cause severe irritation, and possible eye burns. Lachrymator. May cause chemical conjunctivitis and corneal damage. May cause chemical conjunctivitis.
【Ingestion】

May cause severe and permanent damage to the digestive tract. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 34 36
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1760
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

127
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

2
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Decomposition】

Irritating and toxic fumes and gases.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1760
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2903 69 90
Company Name: J & K SCIENTIFIC LTD.
Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
WebSite: http://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel: 4006608290; 18621169109
Fax: 86-21-61259102
WebSite: https://www.meryer.com/cn/index/
Company Name: future industrial shanghai co., ltd
Tel: 400-0066400 13621662912
Fax: 021-55660885
WebSite: http://www.jonln.com
Company Name: Alfa Aesar
Tel: 400-6106006
Fax: 021-67582001/03/05
WebSite: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.
Tel: 021-67121386
Fax: 021-67121385
WebSite: https://www.tcichemicals.com/CN/zh/
Company Name: Yangzhou Aoxin Chemical Co., Ltd
Tel: 0514-87754778 13901446058
Fax: +86-514-87752291
WebSite: http://www.aochem.com/
Company Name: Beijing dtftchem Technology Co., Ltd.
Tel: 010-60275820 13031183356
Fax: 010-60270825
WebSite: www.dtfchem.com
Company Name: Energy Chemical
Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
WebSite: http://www.energy-chemical.com