1-Naphthalenesulfonic acid(85-47-2)

Contents

Product Identification	Back to Contents
【Product Name】 1-Naphthalenesulfonic acid
【Synonyms】 1-Sulfonaphthalene a-Naphthalenesulfonic acid HT 907 Naphthalene-1-sulfonic acid
【CAS】 85-47-2
【Formula】 C10H8O3S
【Molecular Weight】 208.24
【EINECS】 201-610-1
【Merck】 12,6463
【Beilstein/Gmelin】 2099069
【Beilstein Reference】 4-11-00-00521
【EC Class】 irritant

Physical and Chemical Properties	Back to Contents
【Appearance】 Grey powder.
【Solubility in water】 Very soluble
【Melting Point】 139 - 140
【Boiling Point】 392
【pKa/pKb】 0.17 (pKa)
【Partition Coefficient】 2.19
【Usage】 Production of naphthol.

First Aid Measures	Back to Contents
【Ingestion】 Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】 Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
【Skin】 Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】 Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Handling and Storage	Back to Contents
【Storage】 Keep container closed when not in use. Corrosives area. Store in a cool, dry area away from incompatible substances.
【Handling】 Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.

Hazards Identification	Back to Contents
【Inhalation】 Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
【Skin】 Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】 Causes eye burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】 May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
【Hazards】 When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】 R 36/37/38
【EC Safety Phrase】 S 26
【UN (DOT)】 2583

Exposure Controls/Personal Protection	Back to Contents
【Personal Protection】 Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】 A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】 Effects may be delayed.
【Poison Class】 4

Fire Fighting Measures	Back to Contents
【Fire Fighting】 Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】 Combustible material: may burn but does not ignite readily.

Accidental Release Measures	Back to Contents
【Small spills/leaks】 Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity	Back to Contents
【Disposal Code】 4
【Incompatibilities】 Organic materials, metal powders, strong oxidizing agents.
【Stability】 Stable under normal temperatures and pressures.
【Decomposition】 Carbon monoxide, oxides of sulfur, carbon dioxide.
【Combustion Products】 Fire may produce irritating, corrosive and/or toxic gases.

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