ChemicalBook >>Triethanolamine>>TEA(102-71-6)

TEA(102-71-6)

TEA(102-71-6)
Product IdentificationBack to Contents
【Product Name】

TEA
【Synonyms】

2-(Chloromethyl)oxolane
2-(Chloromethyl)tetrahydrofuran
2,2',2-Nitrilotriethanol
2-[(2-Methylpropan-2-yl)oxy]oxolane
Daltogen
Furan, 2-(1,1-dimethylethoxy)tetrahydro-
Sting-Kill
TEA
Trihydroxytriethylamine
Trolamine
【CAS】

3003-84-7
【CAS】

102-71-6
【CAS】

1927-59-9
【Formula】

C5H9ClO
【Formula】

C6H15NO3
【Formula】

C8H16O2
【Molecular Weight】

144.21
【Molecular Weight】

149.19
【Molecular Weight】

120.58
【EINECS】

203-049-8
【EINECS】

217-664-4
【EINECS】

221-102-3
【RTECS】

KL9275000
【RTECS】

LU0350000
【RTECS Class】

Other
【RTECS Class】

Agricultural Chemical and Pesticide; Tumorigen; Mutagen; Primary Irritant
【Merck】

12,9798
【Beilstein/Gmelin】

1280301
【Beilstein/Gmelin】

1699263
【Beilstein/Gmelin】

102716
【Beilstein Reference】

4-04-00-01524
【Beilstein Reference】

5-17-01-00079
【Beilstein Reference】

5-17-03-00058
【EC Class】

flammable, irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid. Benzene-like odor.
【Appearance】

Clear, colorless.
【Appearance】

Colorless to pale yellow viscous liquid with slight ammoniacal odor.
【Solubility in water】

Miscible
【Solubility in water】

Soluble
【Melting Point】

21.6
【Boiling Point】

335.4
【Boiling Point】

127
【Boiling Point】

150
【Vapor Pressure】

8E-6 (25 C)
【Density】

0.9097 g/cm3 (20 C)
【Density】

1.118 g/cm3 (12 C)
【Density】

1.13 g/cm3 (20 C)
【pKa/pKb】

6.24 (pKb)
【Partition Coefficient】

-1.82
【Heat Of Vaporization】

67.0 kJ/mol
【Heat Of Combustion】

-3790 kJ/mol
【Usage】

Insecticide, microbiocide, adjuvan.
【Vapor Density】

4.97
【Vapor Density】

5.14
【Saturation Concentration】

<13 ppm at 20 C
【Refractive Index】

1.42 (20 C)
【Refractive Index】

1.4592 (12 C)
【Refractive Index】

1.4852 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid if irritation or symptoms occur.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

Vapors may cause dizziness or suffocation. May cause irritation or burns.
【Inhalation】

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid if irritation develops or persists. Wash clothing before reuse. Flush skin with plenty of soap and water.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Skin】

May cause irritation or burns.
【Skin】

May cause skin irritation.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

See Skin.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame.
【Storage】

Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. Do not expose to air. Store protected from moisture. Store protected from light. Store under an inert atmosphere.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Store protected from light. Handle under an inert atmosphere. Store protected from air. Discard contaminated shoes.
【Handling】

Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

No adverse effects expected since triethanolamine has a low vapor pressure.
【Skin】

May cause irritation, redness, and pain, especially on prolonged or repeated contact.
【Eyes】

Corrosive. Contact causes severe irritation, burns, redness, and pain. May cause irritation, redness, pain, and corneal damage.
【Ingestion】

May cause burns in the mouth, pharynx, and esophagus, abdominal pain, nausea, vomiting and diarrhea.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 10
【EC Risk Phrase】

R 10 36/37/38
【EC Risk Phrase】

R 36/38
【EC Safety Phrase】

S 23 24/25
【EC Safety Phrase】

S 26 36
【EC Safety Phrase】

S 26 37/39
【UN (DOT)】

1993
【UN (DOT)】

2733
【UN (DOT)】

3271
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Personal Protection】

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Respirators】

Wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Breathing air quality must meet the requirements of the OSHA respiratory protection standard (29CFR1910.134). This substance has unknown warning properties. Where respirators are required, you must have a written program covering the basic requirements in the OSHA respirator standard. These include training, fit testing, medical approval, cleaning, maintenance, cartridge change schedules, etc. See 29CFR1910.134 for details.
【Exposure Effects】

Effects may be delayed.
【Exposure Effects】

May cause liver and kidney damage. Prolonged or repeated contact may cause skin necrosis and/or ulceration of the skin.
【Exposure limit(s)】

TLV: ppm; 5 mg/m3 (ACGIH 1993-1994)
【Poison Class】

3
【Poison Class】

5
Fire Fighting MeasuresBack to Contents
【Flash Point】

34
【Flash Point】

47
【Flash Point】

179
【Autoignition】

315
【Fire Fighting】

Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam. Use water spray or fog; do not use straight streams.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Extinguishing media: Water may be ineffective. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Upper exp. limit】

8.5
【Lower exp. limit】

1.3
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
【Fire Potential】

Slightly flammable. Combustion requires preheating. Moderate hazard.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Place under an inert atmosphere.
【Small spills/leaks】

Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

5
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Stability】

Stable under normal temperatures and pressures.
【Stability】

Stable under ordinary conditions of use and storage. Darkens on exposure to air or light.
【Incompatibilities】

Strong oxidizing agents.
【Incompatibilities】

Moisture, opper, copper alloys, galvanized iron, acids, and oxidizers
【Incompatibilities】

Oxidizing agents.
【Decomposition】

Irritating and toxic fumes and gases.
【Decomposition】

Carbon monoxide, carbon dioxide, nitric oxide (NOx) and ammonia (NH3) fumes.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
【Combustion Products】

Poisonous gases, such as NOx, may be produced
Transport InformationBack to Contents
【UN Number】

1993
【UN Number】

2733
【UN Number】

3271
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2922 13 10
【HS Code】

2932 19 00
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