1656-63-9

三硫代亚磷酸三(十二烷基)脂(1656-63-9)红外图谱(IR1)

分子式:C36H75PS3

分子量: 635.15

InChI:InChI=1S/C36H75PS3/c1-4-7-10-13-16-19-22-25-28-31-34-38-37(39-35-32-29-26-23-20-17-14-11-8-5-2)40-36-33-30-27-24-21-18-15-12-9-6-3/h4-36H2,1-3H3

InChIKey: JZNDMMGBXUYFNQ-UHFFFAOYSA-N

Smiles:P(SCCCCCCCCCCCC)(SCCCCCCCCCCCC)SCCCCCCCCCCCC

Mass

MS-NW-5441          
tridodecyl trithiophosphite
C36H75PS3           (Mass of molecular ion:    634)

   Source Temperature: 190 °C
   Sample Temperature: 140 °C
   Direct, 75 eV

      27.0      17.4
      28.0       3.9
      29.0      35.2
      39.0      14.1
      40.0       2.5
      41.0      72.6
      42.0      13.8
      43.0     100.0
      44.0       3.6
      45.0       3.9
      46.0       1.2
      47.0       8.4
      53.0       5.7
      54.0       7.0
      55.0      61.7
      56.0      21.8
      57.0      92.4
      58.0       4.2
      59.0       2.0
      60.0       5.6
      61.0       5.9
      63.0       4.4
      65.0       1.1
      67.0      10.5
      68.0       8.1
      69.0      37.4
      70.0      16.3
      71.0      44.5
      72.0       2.7
      73.0       2.4
      74.0       1.0
      79.0       1.5
      81.0       5.8
      82.0       7.9
      83.0      22.5
      84.0      10.0
      85.0      25.3
      86.0       1.9
      87.0      12.7
      88.0       2.2
      89.0       4.9
      95.0       3.3
      96.0       4.4
      97.0      15.0
      98.0       6.5
      99.0       6.8
     101.0       6.8
     103.0       1.1
     105.0       1.3
     109.0       1.5
     110.0       1.7
     111.0       6.9
     112.0       3.6
     113.0       4.4
     115.0       2.8
     119.0       1.0
     125.0       2.9
     126.0       1.8
     127.0       2.2
     129.0       2.1
     139.0       1.3
     140.0       2.9
     143.0       1.6
     145.0       1.6
     157.0       1.2
     159.0       1.1
     168.0       5.5
     169.0       1.6
     173.0       1.7
     187.0       1.2
     199.0       4.7
     200.0       7.3
     201.0      62.3
     202.0      14.6
     203.0       4.7
     229.0       3.3
     230.0       1.0
     231.0       5.5
     232.0       1.7
     233.0       1.3
     234.0       1.4
     263.0       1.0
     264.0       3.6
     265.0       8.1
     266.0       1.9
     267.0       1.4
     297.0       1.5
     298.0       1.7
     299.0       1.2
     402.0       3.6
     403.0       1.2
     432.0       1.5
     433.0      16.7
     434.0       5.5
     435.0       2.4
     465.0       1.0
     466.0       2.1
     467.0       1.3
     634.0       3.9
     635.0       1.8

90 MHz in CDCl3

¹H NMR	89.56 MHz
C₃₆ H₇₅ P S₃	0.04 ml : 0.5 ml CDCl₃
tridodecyl trithiophosphite

    Assign.     Shift(ppm)

      A             2.81
      B             1.70
      C             1.26
      D             0.89

     Hz     ppm     Int.

    126.44   1.412     34
    124.19   1.387     45
    121.56   1.358     57
    112.88   1.261   1000
     84.13   0.940     45
     81.88   0.915     36
     81.25   0.908     35
     78.94   0.882    146
     72.94   0.815     32

in CDCl3