35299-71-9

2,6-di(2-thienyl)pyridine(35299-71-9)质谱(MS)

产品名称:2,6-di(2-thienyl)pyridine

CAS:35299-71-9

分子式:C13H9NS2

分子量: 243.35

InChI:InChI=1S/C13H9NS2/c1-4-10(12-6-2-8-15-12)14-11(5-1)13-7-3-9-16-13/h1-9H

InChIKey: LCLYDMCIQMLZFX-UHFFFAOYSA-N

Smiles:C1(C2SC=CC=2)=NC(C2SC=CC=2)=CC=C1

¹HNMR

¹³CNMR

IR1

Mass

MS-IW-8143          
2,6-di(2-thienyl)pyridine
C13H9NS2            (Mass of molecular ion:    243)

   Source Temperature: 140 °C
   Sample Temperature: 100 °C
   Direct, 75 eV

      39.0       1.3
      45.0       1.7
      63.0       1.3
      69.0       1.3
      89.0       1.8
      99.5       3.6
     105.0       1.0
     108.0       2.7
     116.0       1.0
     121.5       6.2
     122.0       1.2
     133.0       1.0
     134.0       1.5
     154.0       1.0
     159.0       1.0
     160.0       1.8
     171.0       1.0
     197.0       1.2
     198.0       2.7
     199.0       2.2
     209.0       1.9
     210.0       8.7
     211.0       1.6
     217.0       1.0
     241.0       1.6
     242.0      11.5
     243.0     100.0
     244.0      17.0
     245.0      10.0
     246.0       1.4

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₃ H₉ N S₂	0.006 g : 0.5 ml CDCl₃
2,6-di(2-thienyl)pyridine

    Assign.     Shift(ppm)

      A             7.659
      B             7.631
      C             7.485
      D             7.400
      E             7.113
     
     J(A,C)=7.8HZ
     J(B,D)=1.2HZ
     J(B,E)=3.8HZ
     J(D,E)=5.1HZ

     Hz     ppm     Int.

   3069.95   7.682    235
   3062.50   7.663    312
   3061.65   7.661    327
   3054.20   7.643    405
   3052.12   7.637    654
   3051.03   7.635    661
   3048.46   7.628    671
   3047.36   7.626    650
   2994.63   7.494   1000
   2986.82   7.474    700
   2963.50   7.416     33
   2960.94   7.409    604
   2959.72   7.406    596
   2955.81   7.396    664
   2954.71   7.394    638
   2847.29   7.125    643
   2843.51   7.116    665
   2842.16   7.112    643
   2838.50   7.103    599

in CDCl3

liquid film