别名
2-丁基-N,N,N′N′-四甲基-二杂戊硼烷-(4S,5S)-二甲酰胺
应用
Butylboronic acid N,N,N′,N′-tetramethyl-D-tartaric acid diamide is a dioxaborolane ligand that can be used to prepare:Enantioenriched spiropentanes via zinc catalyzed cyclopropanation of corresponding hydroxymethylallenes. 1,2,3-trisubstituted cyclopropane derivatives by asymmetric cyclopropanation of allylic alcohols in the presence of zinc reagents. Glycolipids plakosides A, B, and their derivatives by Sharpless asymmetric dihydroxylation and cyclopropanation reaction.
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司
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