Chemical Safety Data Sheet MSDS / SDS

4-DIAZO-N-ETHYL-N-(2-HYDROXYETHYL)ANILINE CHLORIDE ZINC CHLORIDE

Revision Date:2026-03-20Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: 4-DIAZO-N-ETHYL-N-(2-HYDROXYETHYL)ANILINE CHLORIDE ZINC CHLORIDE
  • CBnumber: CB1188556
  • CAS: 13532-96-2
  • EINECS Number: 236-886-2
  • Synonyms: hloride(zncl2) ;Einecs 236-886-2

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 010-86108875

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Symbol(GHS)
  • Signal wordWarning
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P501 Dispose of contents/container to..…
Hazard statements
H228 Flammable solid

SECTION 3: Composition/information on ingredients

Substance

  • Product name: 4-DIAZO-N-ETHYL-N-(2-HYDROXYETHYL)ANILINE CHLORIDE ZINC CHLORIDE
  • Synonyms: hloride(zncl2) ;Einecs 236-886-2
  • CAS: 13532-96-2
  • EC number: 236-886-2
  • MF: C10H14Cl3N3OZn
  • MW: 363.97

SECTION 4: First aid measures

If inhaled

Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.

In case of skin contact

Take off all contaminated clothing immediately. Wash off with soap and plenty of water. Call a POISON CENTER or doctor/ physician if you feel unwell.

In case of eye contact

Rinse with plenty of water. If easy to do, remove contact lens, if worn. If eye irritation persists: Get medical advice/ attention.

If swallowed

Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.

Most important symptoms and effects, both acute and delayed

None known.

SECTION 5: Firefighting measures

Suitable extinguishing media

Dry powder, Foam, Water spray, Carbon dioxide (CO2)

Specific hazards during fire fighting

May explode in fire.

Specific extinguishing methods

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Immediately evacuate personnel to safe areas. Cool closed containers exposed to fire with water spray. Remove undamaged containers from fire area if it is safe to do so.

Special protective equipment for fire-fighters

Use personal protective equipment.

NFPA 704

2
2
2
HEALTH 2 Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
FIRE 2 Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur and multiple finely divided suspended solids that do not require heating before ignition can occur. Flash point between 37.8 and 93.3 °C (100 and 200 °F). (e.g. diesel fuel, sulfur)
REACT 2 Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Wear suitable protective equipment. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off, etc.

Environmental precautions

Prevent product from entering drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust.

SECTION 7: Handling and storage

Handling

Technical measures
Prevent dispersion of dust. Take precautionary measures against static discharge. Use explosion-proof equipment.
Local/Total ventilation
Ensure adequate ventilation. Use a local exhaust ventilation.
Advice on safe handling
Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not subject to grinding, shock or friction. Wash hands and face thoroughly after handling.
Avoidance of contact
Oxidizing agents

Storage

Conditions for safe storage
Keep container tightly closed. Store in a cool and shaded area. Use explosion-proof equipment. Avoid shock and friction.

SECTION 8: Exposure controls/personal protection

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.

Engineering measures

Install a closed system or local exhaust.
Also install safety shower and eye bath.

Personal protective equipment

Respiratory protection
Dust mask
Eye/face protection
Safety glasses
Face-shield
Skin and body protection
Protective suit
Hand protection
Protective gloves *Use personal protective equipment(PPE) approved under appropriate government standards and follow local and national regulations.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Physical statepowder to crystal
  • Appearancesolid
  • Coloryellow - orange
  • OdorNo data available
  • Odor ThresholdNo data available
  • pHNo data available
  • Melting point/freezing pointNo data available
  • Boiling point/boiling rangeNo data available
  • Flash pointNo data available
  • Evaporation rateNo data available
  • FlammabilityNo data available
  • Upper explosion limit / Upper flammability limitNo data available
  • Lower explosion limit / Lower flammability limitNo data available
  • Vapor pressureNo data available
  • Water solubilitysoluble
  • Solubility in other solventsNo data available
  • Partition coefficient: n-octanol/waterNo data available
  • Autoignition temperatureNo data available
  • Decomposition temperatureNo data available
  • Viscosity, dynamicNo data available
  • Viscosity, kinematicNo data available
  • Molecular weight591.66 g/mol

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under normal conditions.

Possibility of hazardous reactions

May explosively decompose on heating, shock, friction, etc.

Conditions to avoid

Heat. Electrical spark Open flame Electrostatic discharge Avoid shock and friction.

Incompatible materials

Oxidizing agents

Hazardous decomposition products

Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx), Hydrogen chloride gas, Metal oxides

SECTION 11: Toxicological information

Acute toxicity

Product

Acute oral toxicity

Assessment: The component/mixture is moderately toxic after single ingestion.

Acute inhalation toxicity

Assessment: The component/mixture is moderately toxic after short term inhalation.

Acute dermal toxicity

Assessment: The component/mixture is moderately toxic after single contact with skin.

Components

4-Diazo-N-ethyl-N-(2-hydroxyethyl)aniline Chloride Zinc Chloride

Acute oral toxicity

Assessment: The component/mixture is moderately toxic after single ingestion.

Acute inhalation toxicity

Assessment: The component/mixture is moderately toxic after short term inhalation.

Acute dermal toxicity

Assessment: The component/mixture is moderately toxic after single contact with skin.

Acute toxicity (other routes of administration)

LD50 (Mouse): 56 mg/kg Application Route: Intravenous

Skin corrosion/irritation

Classified based on available data. For more details, see section 2.

Serious eye damage/eye irritation

Classified based on available data. For more details, see section 2.

Respiratory or skin sensitization

Classified based on available data. For more details, see section 2.

Germ cell mutagenicity

Classified based on available data. For more details, see section 2.

Carcinogenicity

Classified based on available data. For more details, see section 2.

Reproductive toxicity

Classified based on available data. For more details, see section 2.

STOT-single exposure

Classified based on available data. For more details, see section 2.

STOT-repeated exposure

Classified based on available data. For more details, see section 2.

Repeated dose toxicity

Classified based on available data. For more details, see section 2.

Aspiration toxicity

Classified based on available data. For more details, see section 2.

RTECS No.

KK9240000 (4-Diazo-N-ethyl-N-(2-hydroxyethyl)aniline Chloride Zinc Chloride)

SECTION 12: Ecological information

Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

SECTION 13: Disposal considerations

Disposal methods

Waste from residues
Disposal in accordance with local and national regulations. Take precautions against ignition or explode. Entrust disposal to a licensed waste disposal company.
Contaminated packaging
Disposal in accordance with local and national regulations. Before disposal of used container, remove contents completely.

SECTION 14: Transport information

International Regulations

IATA-DGR

UN/ID No.
UN 1325
Proper shipping name
Flammable solid, organic, n.o.s.
Class
4.1
Packing group
III

IMDG-Code

UN number
UN 1325
Proper shipping name
FLAMMABLE SOLID, ORGANIC, N.O.S.
Class
4.1
Packing group
III
EmS Code
F-A, S-G

Domestic regulation

GB 6944/12268

UN number
UN 1325
Proper shipping name
FLAMMABLE SOLID, ORGANIC, N.O.S.
Class
4.1
Packing group
III

SECTION 15: Regulatory information

Measures on the Environmental Administration of New Chemical Substances Registration

Registration/Notification number
B1A232214742
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.

The ingredients of this product are reported in the following inventories

CH BAGREG
On the inventory, or in compliance with the inventory
TSCA
Substance(s) not active on TSCA inventory
AICS
Not in compliance with the inventory
DSL
None of the components of this product are on the Canadian DSL, but all are on the NDSL 4-Diazo-N-ethyl-N-(2-hydroxyethyl)aniline Chloride Zinc Chloride
ENCS
On the inventory, or in compliance with the inventory
ISHL
On the inventory, or in compliance with the inventory
KECI
On the inventory, or in compliance with the inventory
PICCS
Not in compliance with the inventory
IECSC
Not in compliance with the inventory
NZIoC
Not in compliance with the inventory

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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