Bis(2-ethylhexyl)amine
Product identifier
- Product name: Bis(2-ethylhexyl)amine
- CBnumber: CB7202470
- CAS: 106-20-7
- EINECS Number: 203-372-4
- Synonyms: Bis(2-Ethylhexyl)Amine,D2H
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 400-158-6606
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
Substance
- Product name: Bis(2-ethylhexyl)amine
- Synonyms: Bis(2-Ethylhexyl)Amine,D2H
- CAS: 106-20-7
- EC number: 203-372-4
- MF: C16H35N
- MW: 241.46
Description of first aid measures
General adviceMost important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
Extinguishing media
Suitable extinguishing mediaSpecial hazards arising from the substance or mixture
Carbon oxides Nitrogen oxides (NOx) Combustible.
Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
NFPA 704
| HEALTH | 2 | Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine) | |
| FIRE | 1 | Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia) | |
| REACT | 0 | Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2) | |
| SPEC. HAZ. |
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.
Chemizorb?). Dispose of properly. Clean up affected area.
Reference to other sections
For disposal see section 13.
Precautions for safe handling
Advice on safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
control parameter
Hazard composition and occupational exposure limitsExposure controls
Personal protective equipmentUse equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Full contact
Material: butyl-rubber
Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject? (KCL 898)
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Splash contact Material: Viton?
Minimum layer thickness: 0,7 mm Break through time: 120 min
Material tested:Vitoject? (KCL 890 / Aldrich Z677698, Size M)
protective clothing
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Do not let product enter drains.
Information on basic physicochemical properties
- Appearanceclear liquid
- OdourNo data available
- Odour ThresholdNo data available
- pH9 at 0,01 g/l at 25 °C - DIN 19268
- Melting point/freezing pointMelting point:< -20 °C
- Initial boiling point and boiling range123 °C at 7 hPa - lit.
- Flash point130 °C - Pensky-Martens closed cup - ISO 2719
- Evaporation rateNo data available
- Flammability (solid, gas)No data available
- Upper/lower flammability or explosive limits Upper explosion limit: 3,7 %(V) Lower explosion limit: 0,6 %(V)
- Vapour pressure 0,002 hPa at 20 °C - OECD Test Guideline 104
- Vapour density No data available
- Relative density0,805 g/cm3 at 25 °C - lit.
- Water solubility0,014 g/l at 20 °C - OECD Test Guideline 105- slightly soluble
- Partition coefficient: n-octanol/waterlog Pow: 7,3 at 25 °C - OECD Test Guideline 117 - Bioaccumulation is not expected.
- Autoignition temperature245 °C at 1.001 hPa - DIN 51794
- Decomposition temperatureNo data available
- ViscosityViscosity, kinematic: 4,58 mm2/s at 20 °C - ASTM D 4452,79 mm2/s at 40 °C - ASTM D 445 Viscosity, dynamic: 3,68 mPa.s at 20 °C - ASTM D 445
- Explosive propertiesNo data available
- Oxidizing propertiesNo data available
Other safety information
Surface tension 48 mN/m at 0,013g/l at 20 °C
- OECD Test Guideline 115 Dissociation constant ca.10,59 at 25 °C
Reactivity
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Exothermic reaction with:
acids
Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines!
Conditions to avoid
Strong heating.
Incompatible materials
no information available
Hazardous decomposition products
In the event of fire: see section 5
Information on toxicological effects
Acute toxicity(OECD Test Guideline 401)
Symptoms: After swallowing: burns in mouth, throat, oesophagus and gastrointestinal tract.
LC50 Inhalation - Rat - male and female - 4 h - 0,91 mg/l (OECD Test Guideline 403)
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
LD50 Dermal - Rabbit - 956 mg/kg Remarks: (Lit.)
Result: Causes burns. - 3 min - 1 h Remarks: (ECHA)
Result: Severe irritations Remarks: Causes eye burns. Causes serious eye damage.
Salmonella typhimurium Result: negative
In vitro mammalian cell gene mutation test Chinese hamster lung cells
Result: negative Micronucleus test
Chinese hamster lung cells Result: negative
Acute oral toxicity - After swallowing: burns in mouth, throat, oesophagus and gastrointestinal tract.
Acute inhalation toxicity - mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Toxicity
(DIN 38412 part 15)
static test EC50 - Daphnia magna (Water flea) - 2,2 mg/l - 48 h (Directive 67/548/EEC, Annex V, C.2.)
mg/l - 72 h (DIN 38412)
Persistence and degradability
Biodegradability aerobic - Exposure time 39 d
Result: 40 - 50 % - Not readily biodegradable. (OECD Test Guideline 301B)
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
Discharge into the environment must be avoided.
Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
UN number
ADR/RID: 2922 IMDG: 2922 IATA: 2922
UN proper shipping name
ADR/RID: CORROSIVE LIQUID, TOXIC, N.O.S. (2-Ethyl-N-(2-ethylhexyl)-1-hexanamine) IMDG: CORROSIVE LIQUID, TOXIC, N.O.S. (2-Ethyl-N-(2-ethylhexyl)-1-hexanamine) IATA: Corrosive liquid, toxic, n.o.s. (2-Ethyl-N-(2-ethylhexyl)-1-hexanamine)
Transport hazard class(es)
ADR/RID: 8 (6.1) IMDG: 8 (6.1) IATA: 8 (6.1)
Packaging group
ADR/RID: II IMDG: II IATA: II
Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
Special precautions for user
No data available
Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulations on the Safety Management of Hazardous ChemicalsAbbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/
【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.