Chemical Safety Data Sheet MSDS / SDS

Chloramine-T trihydrate

Revision Date:2023-11-29Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

Product name: Chloramine-T trihydrate
CBnumber: CB6157601
CAS: 7080-50-4
EINECS Number: 615-172-8
Synonyms: chloramine t trihydrate,chloramine trihydrate

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

Company Identification

Company: Chemicalbook
Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordDanger

Precautionary statements

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405 Store locked up.

P501 Dispose of contents/container to..…

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P284 Wear respiratory protection.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P270 Do not eat, drink or smoke when using this product.

P264 Wash skin thouroughly after handling.

P264 Wash hands thoroughly after handling.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Hazard statements

H302 Harmful if swallowed

H314 Causes severe skin burns and eye damage

H318 Causes serious eye damage

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled

SECTION 3: Composition/information on ingredients

Substance

Product name: Chloramine-T trihydrate
Synonyms: chloramine t trihydrate,chloramine trihydrate
CAS: 7080-50-4
EC number: 615-172-8
MF: C7H11ClNNaO3S
MW: 247.67

SECTION 4: First aid measures

Description of first aid measures

General advice

First aiders need to protect themselves. Show this material safety data sheet to the doctor

If inhaled

After inhalation: fresh air. Call in physician.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

In case of eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Hydrogen chloride gas Sodium oxides

Not combustible.

Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.

Ambient fire may liberate hazardous vapours.

Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

NFPA 704

HEALTH	3	Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
FIRE	1	Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
REACT	1	Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area. Avoid generation of dusts.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed. Dry. Keep locked up or in an area accessible only to qualified or authorized persons.

Do not store near acids.

Store under inert gas. Air sensitive.

Storage class

Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:KCL 741 Dermatril? L

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:KCL 741 Dermatril? L

Body Protection

protective clothing

Respiratory protection

required when dusts are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Recommended Filter type: Filter type P2

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

Appearanceoff-white powder
OdourNo data available
Odour ThresholdNo data available d) pH 8,0 - 10,0 at 50 g/l at 20 °C Melting point/freezing point Initial boiling point and boiling range Melting point/range: 167 - 170 °C No data available Flash point 192 °C - closed cup Evaporation rate No data available Flammability (solid, gas) Upper/lower flammability or explosive limits No data available No data available Vapour pressure No data available Vapour density No data available Density No data available Relative density No data available Water solubility soluble Partition coefficient: n-octanol/water Autoignition temperature No data available No data available Decomposition No data available temperature Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: No data available Explosive properties No data available Oxidizing properties none
Melting point/freezing pointMelting point/range: 167 - 170 °C
Initial boiling point and boiling range167-170 °C(lit.)
Flash point192 °C - closed cup
Evaporation rate92 °C
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limitsNo data available
Vapour pressure No data available
Vapour density No data available
Relative densityNo data available No data available
Water solubilitysoluble
Partition coefficient: n-octanol/waterH2O: passes test
Autoignition temperatureNo data available
Decomposition temperatureNo data available
ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
Explosive propertiesNo data available
Oxidizing propertiesnone

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

Forms explosive mixtures with air on intense heating.

A range from approx. 15 Kelvin below the flash point is to be rated as critical. Contact with acids liberates toxic gas.

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

Generates dangerous gases or fumes in contact with:

Acids

Conditions to avoid

Strong heating.

Incompatible materials

Do not store near acids., Strong oxidizing agents, Ammonia

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - male and female - 935 mg/kg (OECD Test Guideline 401)
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine T
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach.
LC50 Inhalation - Rat - male and female - 4 h - > 0,275 mg/l (OECD Test Guideline 403)
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine T
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Dermal

Skin corrosion/irritation

Skin - Rabbit
Result: Causes burns. - 4 h
(OECD Test Guideline 404) Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine T

Serious eye damage/eye irritation

Eyes - Rabbit
Result: Causes serious eye damage. - 72 h (OECD Test Guideline 405)
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine T Causes serious eye damage.

Respiratory or skin sensitization

May cause allergy or asthma symptoms or breathing difficulties if inhaled. (ECHA) (anhydrous substance)

Germ cell mutagenicity

Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471
Result: negative
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine TTest Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476
Result: negative
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine T Test Type: Micronucleus test
Species: Mouse
Cell type: Red blood cells (erythrocytes) Application Route: Oral
Method: OECD Test Guideline 474 Result: negative
Remarks: (anhydrous substance)
The value is given in analogy to the following substances: Chloramine T

Carcinogenicity

No data available

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Toxicity

LD50 orally in Rabbit: 935 mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish

static test LC50 - Oncorhynchus mykiss (rainbow trout) - 100 mg/l - 96 h

(US-EPA)

Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Chloramine T

Toxicity to daphnia and other aquatic invertebrates

EC50 - Daphnia magna (Water flea) - 4,5 mg/l - 48 h Remarks: (IUCLID)

NOEC - Daphnia magna (Water flea) - 1,1 mg/l - 21 d (OECD Test Guideline 202)

Toxicity to algae

static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 13 mg/l - 96 h

(OECD Test Guideline 201) Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Chloramine T

Toxicity to bacteria

static test EC50 - activated sludge - 37 mg/l - 3 h (OECD Test Guideline 209)

Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Chloramine T

Persistence and degradability

Biodegradability aerobic - Exposure time 28 d

Result: 92 % - Readily biodegradable. (OECD Test Guideline 301D) Remarks: (anhydrous substance)

The value is given in analogy to the following substances: Chloramine

Bioaccumulative potential

Bioaccumulation Oncorhynchus mykiss (rainbow trout) - 1 h

at 11,8 °C - 20 mg/l(Chloramine-T trihydrate)

Bioconcentration factor (BCF): 2,2

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

Discharge into the environment must be avoided.

SECTION 13: Disposal considerations

Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and

containers, or contact us there if you have further questions.

SECTION 14: Transport information

UN number

ADR/RID: 3263 IMDG: 3263 IATA: 3263

UN proper shipping name

ADR/RID: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Chloramine-T trihydrate) IMDG: CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Chloramine-T trihydrate)

IATA: Corrosive solid, basic, organic, n.o.s. (Chloramine-T trihydrate)

Transport hazard class(es)

ADR/RID: 8 IMDG: 8 IATA: 8

Packaging group

ADR/RID: II IMDG: II IATA: II

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

United States Toxic Substances Control Act (TSCA) Inventory:Not Listed. website: https://www.epa.gov/

Korea Existing Chemicals List (KECL):Not Listed. website: http://ncis.nier.go.kr

European Inventory of Existing Commercial Chemical Substances (EINECS):Not Listed. website: https://echa.europa.eu/

EC Inventory:Not Listed.

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

SECTION 16: Other information

Abbreviations and acronyms

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
CAS: Chemical Abstracts Service
EC50: Effective Concentration 50%
IATA: International Air Transportation Association
IMDG: International Maritime Dangerous Goods
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
STEL: Short term exposure limit
TWA: Time Weighted Average

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.