Flammable gases, Category 1A, Flammable gas
Skin irritation, Category 2
Serious eye damage, Category 1
Acute toxicity - Category 1, Inhalation
Specific target organ toxicity – single exposure, Category 3
Danger
H220 Extremely flammable gas
H315 Causes skin irritation
H318 Causes serious eye damage
H330 Fatal if inhaled
H335 May cause respiratory irritation
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P284 [In case of inadequate ventilation] wear respiratory protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P321 Specific treatment (see ... on this label).
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P320 Specific treatment is urgent (see ... on this label).
P319 Get medical help if you feel unwell.
P403 Store in a well-ventilated place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Exposure Routes: inhalation, skin and/or eye contact Symptoms: Irritation eyes, skin, nose, throat, respiratory system; pulmonary edema Target Organs: Eyes, skin, respiratory system (NIOSH, 2016)
no data available
Excerpt from ERG Guide 131P [Flammable Liquids - Toxic]: CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam. LARGE FIRE: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight streams. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
Excerpt from ERG Guide 131P [Flammable Liquids - Toxic]: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. (ERG, 2016)
Use powder, carbon dioxide. NO water. In case of fire: keep cylinder cool by spraying with water. NO direct contact with water.
Evacuate danger area! Consult an expert! Ventilation. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus.
Evacuate danger area! Consult an expert! Ventilation. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus.
Persons not wearing protective equipment and clothing should be restricted from areas of leaks until cleanup has been completed. if ketene is leaked, the following steps should be taken: 1. remove all ignition sources. 2. ventilate the area of leak. 3. stop flow of gas. disposal methods: ketene may be disposed of by burning at a safe location or in a suitable combustion chamber.
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
The substance cannot be stored or shipped....CANNOT BE...STORED IN A GASEOUS STATE.
TLV: 0.5 ppm as TWA; 1.5 ppm as STEL
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection.
Protective gloves.
Use ventilation, local exhaust or breathing protection.
no data available
COLORLESS GAS
PENETRATING ODOR
-150°C
-56°C
Flammable Gas
no data available
Flammable gas
no data available
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Reacts with water (NIOSH, 2016)
no data available
12600mmHg at 25°C
0.712 g/cm3
1.45 (AIR= 1)
no data available
The substance may readily polymerize. Reacts violently with many organic compounds. Reacts with water. This produces acetic acid. Decomposes in alcohol and ammonia.
no data available
The gas is heavier than air and may travel along the ground; distant ignition possible.KETENE is extremely flammable. Mixtures with air are explosive. Reacts violently with water; reacts vigorously with alcohols, ammonia. Readily polymerizes and cannot be shipped or stored. Is obtained instead as needed from diketene. DIKETENE is extremely flammable. Forms explosive vapor/air mixtures above 33°C. Undergoes a further exothermic polymerization that is retarded by storage in the solid state (below -6.5°C) or by the use of stabilizing additives. This polymerization becomes violent (with risk of fire or explosion) with warming or on contact with acids or bases. Reacts violently with water.
no data available
Water, alcohols, ammonia [Note: Readily polymerizes. Reacts with water to form acetic acid].
no data available
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The substance is irritating to the eyes, skin and respiratory tract. Inhalation of this gas may cause lung oedema. The effects may be delayed. Medical observation is indicated. See Notes.
Repeated or prolonged inhalation may cause effects on the lungs. This may result in emphesema and fibrosis.
A harmful concentration of this gas in the air will be reached very quickly on loss of containment.
no data available
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1955 (For reference only, please check.)
IMDG: UN1955 (For reference only, please check.)
IATA: UN1955 (For reference only, please check.)
ADR/RID: COMPRESSED GAS, TOXIC, N.O.S. (For reference only, please check.)
IMDG: COMPRESSED GAS, TOXIC, N.O.S. (For reference only, please check.)
IATA: COMPRESSED GAS, TOXIC, N.O.S. (For reference only, please check.)
ADR/RID: 2.3 (For reference only, please check.)
IMDG: 2.3 (For reference only, please check.)
IATA: 2.3 (For reference only, please check.)
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
Reacts violently with fire extinguishing agents such as water.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.