Chemical Safety Data Sheet MSDS / SDS
Revision Date:2026-03-20Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 010-86108875

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Signal wordDanger
Precautionary statements
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P403+P235 Store in a well-ventilated place. Keep cool.
P402+P404 Store in a dry place. Store in a closed container.
P370+P378 In case of fire: Use … for extinction.
P422 Store contents under …
P310 Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232 Handle under inert gas. Protect from moisture.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P501 Dispose of contents/container to..…
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P271 Use only outdoors or in a well-ventilated area.
P270 Do not eat, drink or smoke when using this product.
P264 Wash skin thouroughly after handling.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P240 Ground/bond container and receiving equipment.
P233 Keep container tightly closed.
P405 Store locked up.
P309 IF exposed or if you feel unwell:
Hazard statements
H372 Causes damage to organs through prolonged or repeated exposure
H315 Causes skin irritation
H320 Causes eye irritation
H225 Highly Flammable liquid and vapour
H261 In contact with water releases flammable gas
H314 Causes severe skin burns and eye damage
H260 In contact with water releases flammable gases which may ignite spontaneously
H304 May be fatal if swallowed and enters airways
H336 May cause drowsiness or dizziness
H351 Suspected of causing cancer
H373 May cause damage to organs through prolonged or repeated exposure
H302 Harmful if swallowed
H226 Flammable liquid and vapour
H371 May cause damage to organs
H335 May cause respiratory irritation
H318 Causes serious eye damage

SECTION 3: Composition/information on ingredients

Substance

  • Product name: Methylmagnesium Bromide
  • Synonyms: MeMgBr;METHYLMAGNESIUM BROMIDE
  • CAS: 75-16-1
  • EC number: 200-844-1
  • MF: CH3BrMg
  • MW: 119.24

SECTION 4: First aid measures

SECTION 5: Firefighting measures

NFPA 704

3
4
2
W
HEALTH 3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
FIRE 4 Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Includes pyrophoric substances. Flash point below room temperature at 22.8 °C (73 °F). (e.g. acetylene, propane, hydrogen gas)
REACT 2 Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)
SPEC. HAZ. W

SECTION 6: Accidental release measures

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

SECTION 9: Physical and chemical properties

SECTION 10: Stability and reactivity

SECTION 11: Toxicological information

SECTION 12: Ecological information

SECTION 13: Disposal considerations

SECTION 14: Transport information

SECTION 15: Regulatory information

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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