Chemical Safety Data Sheet MSDS / SDS
NITROBENZENE (13C6)
Revision Date:2026-03-21Revision Number:1
Product identifier
- Product name: NITROBENZENE (13C6)
- CBnumber: CB5686823
- CAS: 89059-37-0
- Synonyms: Nitrobenzene-13C?;Nitrobenzene (13C?, 99%)
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P273 Avoid release to the environment.
P201 Obtain special instructions before use.
Hazard statements
H412 Harmful to aquatic life with long lasting effects
H372 Causes damage to organs through prolonged or repeated exposure
H351 Suspected of causing cancer
Substance
- Product name: NITROBENZENE (13C6)
- Synonyms: Nitrobenzene-13C?;Nitrobenzene (13C?, 99%)
- CAS: 89059-37-0
- MF: C6H5NO2
- MW: 129.16
4.1 Description of first-aid measures
General adviceFirst aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
If swallowed
If swallowed: give water to drink (two glasses at most). Seek medical advice immediately.
In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.
In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
4.4 Notes to physician
No data available
5.1 Extinguishing media
Suitable extinguishing mediaWater Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Nitrogen oxides (NOx)
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
Nitrogen oxides (NOx)
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.
Chemizorb®). Dispose of properly. Clean up affected area.
Chemizorb®). Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
Advice on safe handlingWork under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditionsTightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
Storage class
Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
8.1 Control parameters
Ingredients with workplace control parameters| ['Component', 'CAS-No.', 'Value', 'Control\nparameters', 'Basis'] | ['Nitrobenzene-\n13C6', '89059-37-\n0', 'PC-TWA', '2 mg/m3', 'Occupational exposure limits for\nhazardous agents in the\nworkplace - Chemical\nhazardous agents.'] | ['', 'Remarks', 'G2B - Possibly carcinogenic to humans\nSkin', None, None] |
|---|
| ['Component', 'CAS-No.', 'Parameters', 'Value', 'Biological\nspecimen', 'Basis'] | ['Nitrobenzene-\n13C6', '89059-37-\n0', 'Methemoglo\nbin', '1.5% Hb', 'In blood', 'ACGIH -\nBiological\nExposure Indices\n(BEI)'] | ['', 'Remarks', 'During or at the end of the shift', None, None, None] |
|---|
8.2 Exposure controls
Appropriate engineering controlsImmediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
required
Body Protection
protective clothing
Respiratory protection
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains.
Information on basic physicochemical properties
- a) Physical stateliquid
- b) ColorColourless
- c) OdorNo data available
- d) Melting point/freezing pointMelting point/range: 5 - 6 °C
- e) Initial boiling point and boiling range210 - 211 °C - lit.
- f) Flammability (solid, gas)No data available
- g) Upper/lower flammability or explosive limitsUpper explosion limit: 40 %(V)
Lower explosion limit: 1.8 %(V) - h) Flash point88 °C - closed cup
- i) Autoignition temperature482 °C
- j) Decomposition temperatureNo data available
- k) pH8.0 - 8.5 at 1 g/l at 20 °C
- l) ViscosityViscosity, kinematic: No data available
Viscosity, dynamic: No data available - m) Water solubilityNo data available
- n) Partition coefficient n-octanol/waterNo data available
- o) Vapor pressure0.3 hPa at 20 °C 67 hPa at 120 °C
- p) Density1.253 g/cm3 at 25 °C
- Relative density1.253 g/mL at 25 °C
- q) Relative vapor densityNo data available
- r) Particle characteristicsNo data available
- s) Explosive propertiesNo data available
- t) Oxidizing propertiesNo data available
- SolubilityChloroform (Slightly), Methanol (Slightly)
9.2 Other safety information
No data available
10.1 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.2 Possibility of hazardous reactions
No data available
10.3 Conditions to avoid
Strong heating.
10.4 Incompatible materials
Strong oxidizing agents, Strong reducing agents, Strong bases
10.5 Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicityAcute toxicity estimate Oral - 100.1 mg/kg (Expert judgment)
LC50 Inhalation - Rat - 4 h - 2.8 mg/l - vapor
Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Lacrimation.
Behavioral:Tremor.
Cyanosis
The value is given in analogy to the following substances: Nitrobenzene
LD50 Dermal - Rabbit - 760 mg/kg
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Skin corrosion/irritation
LC50 Inhalation - Rat - 4 h - 2.8 mg/l - vapor
Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Lacrimation.
Behavioral:Tremor.
Cyanosis
The value is given in analogy to the following substances: Nitrobenzene
LD50 Dermal - Rabbit - 760 mg/kg
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Skin - Rabbit
Result: No skin irritation - 24 h
Remarks: Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Respiratory or skin sensitization
Result: No skin irritation - 24 h
Remarks: Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
Remarks: The value is given in analogy to the following substances: Nitrobenzene
- Mouse
Result: Did not cause sensitization on laboratory animals.
(OECD Test Guideline 429)
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Germ cell mutagenicity
Result: Did not cause sensitization on laboratory animals.
(OECD Test Guideline 429)
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Test Type: unscheduled DNA synthesis assay
Test system: rat hepatocytes
Method: OECD Test Guideline 482
Result: negative
Remarks:
Test Type: Micronucleus test
Species: Mouse
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Carcinogenicity
Test system: rat hepatocytes
Method: OECD Test Guideline 482
Result: negative
Remarks:
Test Type: Micronucleus test
Species: Mouse
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Suspected human carcinogens
Reproductive toxicity
Presumed human reproductive toxicant
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Specific target organ toxicity - repeated exposure
Inhalation - Causes damage to organs through prolonged or repeated exposure.
- Blood
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Aspiration hazard
- Blood
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Classified based on available data. For more details, see section 2
11.2 Additional Information
Repeated dose toxicity - Rat - male and female - Oral - 28 d - LOAEL (Lowest observed adverse effect level) - 5 mg/kg
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Repeated dose toxicity - Rat - male and female - Inhalation - 14 d
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., Exposure to and/or consumption of alcohol may increase toxic effects., Nausea, Headache, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Repeated dose toxicity - Rat - male and female - Inhalation - 14 d
Remarks: The value is given in analogy to the following substances: Nitrobenzene
Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., Exposure to and/or consumption of alcohol may increase toxic effects., Nausea, Headache, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
12.1 Toxicity
Toxicity to fish flow-through test LC50 - Danio rerio (zebra fish) - 92 mg/l - 96.0 h (OECD Test Guideline 203)
Remarks: The value is given in analogy to the following substances:
Nitrobenzene
Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - 35 mg/l - 48 h and other aquatic Remarks: The value is given in analogy to the following substances: invertebrates Nitrobenzene
Toxicity to algae Growth inhibition EC50 - Chlorella pyrenoidosa - 18 mg/l - 96 h (OECD Test Guideline 201)
Remarks: The value is given in analogy to the following substances:
Nitrobenzene
Toxicity to daphnia NOEC - Daphnia magna (Water flea) - 2.6 mg/l - 21 d and other aquatic Remarks: The value is given in analogy to the following substances: invertebrates(Chronic Nitrobenzene toxicity)
Remarks: The value is given in analogy to the following substances:
Nitrobenzene
Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - 35 mg/l - 48 h and other aquatic Remarks: The value is given in analogy to the following substances: invertebrates Nitrobenzene
Toxicity to algae Growth inhibition EC50 - Chlorella pyrenoidosa - 18 mg/l - 96 h (OECD Test Guideline 201)
Remarks: The value is given in analogy to the following substances:
Nitrobenzene
Toxicity to daphnia NOEC - Daphnia magna (Water flea) - 2.6 mg/l - 21 d and other aquatic Remarks: The value is given in analogy to the following substances: invertebrates(Chronic Nitrobenzene toxicity)
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Endocrine disrupting properties
No data available
12.7 Other adverse effects
No data available
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Offer surplus and non-recyclable solutions to a licensed disposal company.
14.1 UN number
ADR/RID: 1662
IMDG: 1662
IATA-DGR: 1662
IMDG: 1662
IATA-DGR: 1662
14.2 UN proper shipping name
ADR/RID: NITROBENZENE
IMDG: NITROBENZENE
IATA-DGR: Nitrobenzene
IMDG: NITROBENZENE
IATA-DGR: Nitrobenzene
14.3 Transport hazard class(es)
ADR/RID: 6.1
IMDG: 6.1
IATA-DGR: 6.1
IMDG: 6.1
IATA-DGR: 6.1
14.4 Packaging group
ADR/RID: II
IMDG: II
IATA-DGR: II
IMDG: II
IATA-DGR: II
14.5 Environmental hazards
ADR/RID: yes
IMDG Marine pollutant: yes
IATA-DGR: no
IMDG Marine pollutant: yes
IATA-DGR: no
14.6 Special precautions for user
Based on chemical properties, choose appropriate tools and conditions of transport.
Transporting tools shall be equipped with appropriate and sufficient firefighting equipment and emergency leaking installations. If transporting by road, please go along the specified route.
Transporting tools shall be equipped with appropriate and sufficient firefighting equipment and emergency leaking installations. If transporting by road, please go along the specified route.
14.7 Incompatible materials
Strong oxidizing agents, Strong reducing agents, Strong bases
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulatory information
Law on the Prevention and Control of Occupational Diseases
Regulations on Safety Management of Hazardous Chemicals
Catalogue of Hazardous Chemicals : Listed
Regulations on Occupational Labor Protection in the at workplaces where Toxic
Substances Are Used
Catalogue of Highly Toxic Chemicals : Listed
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification number : B1A222214570
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Law on the Prevention and Control of Occupational Diseases
Regulations on Safety Management of Hazardous Chemicals
Catalogue of Hazardous Chemicals : Listed
Regulations on Occupational Labor Protection in the at workplaces where Toxic
Substances Are Used
Catalogue of Highly Toxic Chemicals : Listed
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification number : B1A222214570
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.
Recommended Products
1,3-DINITROBENZENE (13C6) SDS
4,6-DICHLORO-1,3-DINITROBENZENE-13C6 SDS
NITROBENZENE (13C6) SDS