Chemical Safety Data Sheet MSDS / SDS

Potassium Phosphate Monobasic

Revision Date:2024-04-13Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

Product name: Potassium Phosphate Monobasic
CBnumber: CB6122627
CAS: 7778-77-0
EINECS Number: 231-913-4
Synonyms: Potassium dihydrogen phosphate,Monopotassium phosphate

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

Company Identification

Company: Chemicalbook
Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

Symbol(GHS)

Precautionary statements

P264 Wash hands thoroughly after handling.

P264 Wash skin thouroughly after handling.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321 Specific treatment (see … on this label).

P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

P337+P313 IF eye irritation persists: Get medical advice/attention.

Hazard statements

H313 May be harmful in contact with skin

H315 Causes skin irritation

H319 Causes serious eye irritation

SECTION 3: Composition/information on ingredients

Substance

Product name: Potassium Phosphate Monobasic
Synonyms: Potassium dihydrogen phosphate,Monopotassium phosphate
CAS: 7778-77-0
EC number: 231-913-4
MF: H2KO4P
MW: 136.086

SECTION 4: First aid measures

Description of first aid measures

If inhaled

After inhalation: fresh air.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

In case of eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

If swallowed

After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling unwell.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Oxides of phosphorus Potassium oxides

Not combustible.

Ambient fire may liberate hazardous vapours.

Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

NFPA 704

HEALTH	1	Exposure would cause irritation with only minor residual injury (e.g. acetone, sodium bromate, potassium chloride)
FIRE	0	Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride)
REACT	0	Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed. Dry.

Keep in a dry place.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate

government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory protection

required when dusts are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Recommended Filter type: Filter type P1

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

Appearancewhite powder
Odourodorless
Odour ThresholdNot applicable d) pH 4,2 - 4,6 at 20,0 g/l at 20,0 °C Melting point/freezing point Initial boiling point and boiling range Melting point/range: 252,6 °C 450 °C at 1.013 hPa - Regulation (EC) No. 440/2008, Annex, A.2 Flash point No data available Evaporation rate No data available Flammability (solid, gas) Upper/lower flammability or explosive limits No data available No data available Vapour pressure< 0,1 hPa at 25 °C - Regulation (EC) No. 440/2008, Annex, A.4 Vapour density No data available Relative density 2,33 at 21,5 °C - Regulation (EC) No. 440/2008, Annex, A.3 Water solubility 208 g/l at 20 °C - Regulation (EC) No. 440/2008, Annex, A.6- completely soluble Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature - Not applicable for inorganic substances No data available No data available Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: No data available Explosive properties No data available Oxidizing properties No data available
Melting point/freezing pointMelting point/range: 252,6 °C
Initial boiling point and boiling range450 °C at 1.013 hPa - Regulation (EC) No. 440/2008, Annex, A.2
Flash point> 450 °C
Evaporation rateNo data available
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limitsNo data available
Vapour pressure< 0,1 hPa at 25 °C - Regulation (EC) No. 440/2008, Annex, A.4
Vapour density No data available
Relative density2,33 at 21,5 °C - Regulation (EC) No. 440/2008, Annex, A.3
Water solubility208 g/l at 20 °C - Regulation (EC) No. 440/2008, Annex, A.6- completely soluble
Partition coefficient: n-octanol/water- Not applicable for inorganic substances
Autoignition temperatureNo data available
Decomposition temperatureNo data available
Viscosity253 °C
Explosive propertiesNo data available
Oxidizing propertiesNo data available
λmaxλ: 260 nm Amax: 0.046
λ: 280 nm Amax: 0.040

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

Violent reactions possible with:

Acids Bases

Strong oxidizing agents

Conditions to avoid

Exposure to moisture. no information available

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - female - > 2.000 mg/kg (OECD Test Guideline 420)
Remarks:
The value is given in analogy to the following substances: dipotassium hydrogen phosphate LC50 Inhalation - Rat - male and female - 4 h - > 0,83 mg/l
(OECD Test Guideline 403) Remarks:
(in analogy to similar products)
The value is given in analogy to the following substances: sodium dihydrogen phosphate LD50 Dermal - Rabbit - male and female - > 2.000 mg/kg
(OECD Test Guideline 402)

Skin corrosion/irritation

Skin - Rabbit
Result: No skin irritation - 4 h (Draize Test)
Remarks:
(ECHA)

Serious eye damage/eye irritation

Eyes - Rabbit
Result: No eye irritation - 30 s (Draize Test)
Remarks: (ECHA)

Respiratory or skin sensitization

No data available

Germ cell mutagenicity

Micronucleus test Human lymphocytes Result: negative
In vitro mammalian cell gene mutation test mouse lymphoma cells
Result: negative Remarks:
(ECHA)

Carcinogenicity

IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Toxicity

LD50 skin in rabbit: > 4640mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish

semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - > 100 mg/l - 96 h

(OECD Test Guideline 203)

Toxicity to daphnia and other aquatic invertebrates

static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202)

Toxicity to algae

static test ErC50 - Desmodesmus subspicatus (green algae) - > 100 mg/l - 72 h

(OECD Test Guideline 201)

Toxicity to bacteria

static test EC50 - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209)

static test NOEC - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209)

Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

Bioaccumulative potential

Does not bioaccumulate.

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

No data available

SECTION 13: Disposal considerations

Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

SECTION 14: Transport information

UN number

ADR/RID: - IMDG: - IATA: -

UN proper shipping name

ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods

Transport hazard class(es)

ADR/RID: - IMDG: - IATA: -

Packaging group

ADR/RID: - IMDG: - IATA: -

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

Further information

Not classified as dangerous in the meaning of transport regulations.

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

EC Inventory:Listed.

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

SECTION 16: Other information

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.