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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic iridium >Chloro(1,5-cyclooctadiene)iridium(I) dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer Structure
  • ₹3168 - ₹95741
  • Product name: Chloro(1,5-cyclooctadiene)iridium(I) dimer
  • CAS: 12112-67-3
  • MF: C16H24Cl2Ir2
  • MW: 671.7
  • EINECS:235-170-7
  • MDL Number:MFCD00012414
  • Synonyms:DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)];DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM;CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER;CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER;IRIDIUM I CYCLOOCTADIENE CHLORIDE;IRIDIUM CHLORO-1,5-CYCLOOCTADIENE;IRIDIUM COD CHLORIDE;1,5-CYCLOOCTADIENE-IRIDIUM(I) CHLORIDE DIMER
7 prices
Selected condition:

Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 250MG
  • 0.25g
  • 500MG
  • 1g
  • 2G
  • 5g
  • ManufacturerALFA India
  • Product numberALF-012749-01
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Packaging0.25g
  • Price₹3168
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-012749-03
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Packaging1g
  • Price₹14000
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-012749-06
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
  • Packaging5g
  • Price₹95741
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberC1807
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer
  • Packaging250MG
  • Price₹4800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberC1807
  • Product descriptionChloro(1,5-cyclooctadiene)iridium(I) Dimer
  • Packaging1G
  • Price₹16800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683094
  • Product descriptionHS157 Umicore, 97%
  • Packaging500MG
  • Price₹12198.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683094
  • Product descriptionHS157 Umicore, 97%
  • Packaging2G
  • Price₹36874.2
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-012749-01 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 0.25g ₹3168 2022-05-26 Buy
ALFA India ALF-012749-03 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 1g ₹14000 2022-05-26 Buy
ALFA India ALF-012749-06 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 5g ₹95741 2022-05-26 Buy
TCI Chemicals (India) C1807 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 250MG ₹4800 2022-05-26 Buy
TCI Chemicals (India) C1807 Chloro(1,5-cyclooctadiene)iridium(I) Dimer 1G ₹16800 2022-05-26 Buy
Sigma-Aldrich(India) 683094 HS157 Umicore, 97% 500MG ₹12198.9 2022-06-14 Buy
Sigma-Aldrich(India) 683094 HS157 Umicore, 97% 2G ₹36874.2 2022-06-14 Buy

Properties

Melting point :205 °C (dec.)(lit.)
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
form :Powder
color :red to orange
Water Solubility :insoluble
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
InChI :InChI=1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChIKey :XHOSESNLNGITPM-XRGHXPOKSA-L
SMILES :C1C=CCCC=CC1.C1C=CCCC=CC1.Cl[Ir].Cl[Ir] |c:1,5,9,13|

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

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