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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic palladium >Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Structure
  • ₹5472.3 - ₹70418.4
  • Product name: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
  • CAS: 1375325-71-5
  • MF: C24H37ClNPPd
  • MW: 512.41
  • EINECS:
  • MDL Number:MFCD21608496
  • Synonyms:Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2'-amino[1,1'-biphenyl]-2-yl]palladium(II);Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);tBu3PPdG2 catalyst;Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%;P(t-Bu)3 Palladacycle Gen.2
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 250MG
  • 500MG
  • 1G
  • 2G
  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberC2734
  • Product descriptionChloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
  • Packaging1G
  • Price₹20100
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number756482
  • Product descriptionP(t-Bu)3 Pd G2
  • Packaging250MG
  • Price₹5472.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number756482
  • Product descriptionP(t-Bu)3 Pd G2
  • Packaging500MG
  • Price₹10977.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number756482
  • Product descriptionP(t-Bu)3 Pd G2
  • Packaging2G
  • Price₹35808.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number756482
  • Product descriptionP(t-Bu)3 Pd G2
  • Packaging5G
  • Price₹70418.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) C2734 Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) 1G ₹20100 2022-05-26 Buy
Sigma-Aldrich(India) 756482 P(t-Bu)3 Pd G2 250MG ₹5472.3 2022-06-14 Buy
Sigma-Aldrich(India) 756482 P(t-Bu)3 Pd G2 500MG ₹10977.9 2022-06-14 Buy
Sigma-Aldrich(India) 756482 P(t-Bu)3 Pd G2 2G ₹35808.6 2022-06-14 Buy
Sigma-Aldrich(India) 756482 P(t-Bu)3 Pd G2 5G ₹70418.4 2022-06-14 Buy

Properties

Melting point :158-160°C
storage temp. :2-8°C, protect from light, stored under nitrogen
form :Powder
color :yellow
InChI :InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
InChIKey :CCFGXRYKSYUWKT-UHFFFAOYSA-N
SMILES :P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Description

P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies:
  • Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
  • Stille cross-couplings reactions of aryl chloride.
  • Synthesis of chloropeptin I, via Stille cross-coupling reaction.
  • Heck reaction.
  • Negishi cross-coupling reactions.

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