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ChemicalBook >> CAS DataBase List >> Tris(triphenylphosphine)rhodiu

Tris(triphenylphosphine)rhodiu

Tris(triphenylphosphine)rhodiu price.
  • $28 - $6125
  • Product name: Tris(triphenylphosphine)rhodiu
  • CAS: 14694-95-2
  • MF: C54H45ClP3Rh
  • MW: 925.21
  • EINECS:238-744-5
  • MDL Number:MFCD00010016
  • Synonyms:DECARBON;CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODATE (I);CHLORO TRIS ( TRIPHENYL PHOSPHANE ) RHODIUM (1);Chlorotris-(triphenylphosphino)-rhodium;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE POLYMER BOUND;(sp-4-2)-rhodiu
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  • ManufacturerAK Scientific
  • Product numberJ91919
  • Product descriptionTris(triphenylphosphine)rhodium(I) Chloride
  • Packaging250mg
  • Price$71
  • Updated2021-12-16
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  • ManufacturerAlfa Aesar
  • Product number010468
  • Product descriptionChlorotris(triphenylphosphine)rhodium(I), 97%
  • Packaging1g
  • Price$264
  • Updated2023-06-20
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  • ManufacturerAlfa Aesar
  • Product number010468
  • Product descriptionChlorotris(triphenylphosphine)rhodium(I), 97%
  • Packaging5g
  • Price$1255
  • Updated2023-06-20
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  • ManufacturerAlichem
  • Product number14694952
  • Product descriptionTris(triphenylphosphine)chlororhodium
  • Packaging10g
  • Price$238.5
  • Updated2021-12-16
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  • ManufacturerAlichem
  • Product number14694952
  • Product descriptionTris(triphenylphosphine)chlororhodium
  • Packaging25g
  • Price$446.25
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA318556
  • Product descriptionTris(triphenylphosphine)chlororhodium 98%
  • Packaging100mg
  • Price$32
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA321287
  • Product descriptionTris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis
  • Packaging100mg
  • Price$32
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA318556
  • Product descriptionTris(triphenylphosphine)chlororhodium 98%
  • Packaging250mg
  • Price$63
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA321287
  • Product descriptionTris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis
  • Packaging250mg
  • Price$66
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA318556
  • Product descriptionTris(triphenylphosphine)chlororhodium 98%
  • Packaging1g
  • Price$195
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA321287
  • Product descriptionTris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis
  • Packaging1g
  • Price$195
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA318556
  • Product descriptionTris(triphenylphosphine)chlororhodium 98%
  • Packaging5g
  • Price$748
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA321287
  • Product descriptionTris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis
  • Packaging5g
  • Price$748
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0025886
  • Product descriptionTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE 95.00%
  • Packaging1G
  • Price$154.35
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberSY007812
  • Product descriptionTris(triphenylphosphine)rhodium(I) Chloride 11%
  • Packaging250mg
  • Price$70
  • Updated2021-12-16
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  • ManufacturerArctom
  • Product numberSY007812
  • Product descriptionTris(triphenylphosphine)rhodium(I) Chloride 11%
  • Packaging1g
  • Price$230
  • Updated2021-12-16
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Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J91919 Tris(triphenylphosphine)rhodium(I) Chloride 250mg $71 2021-12-16 Buy
Alfa Aesar 010468 Chlorotris(triphenylphosphine)rhodium(I), 97% 1g $264 2023-06-20 Buy
Alfa Aesar 010468 Chlorotris(triphenylphosphine)rhodium(I), 97% 5g $1255 2023-06-20 Buy
Alichem 14694952 Tris(triphenylphosphine)chlororhodium 10g $238.5 2021-12-16 Buy
Alichem 14694952 Tris(triphenylphosphine)chlororhodium 25g $446.25 2021-12-16 Buy
Ambeed A318556 Tris(triphenylphosphine)chlororhodium 98% 100mg $32 2021-12-16 Buy
Ambeed A321287 Tris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis 100mg $32 2021-12-16 Buy
Ambeed A318556 Tris(triphenylphosphine)chlororhodium 98% 250mg $63 2021-12-16 Buy
Ambeed A321287 Tris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis 250mg $66 2021-12-16 Buy
Ambeed A318556 Tris(triphenylphosphine)chlororhodium 98% 1g $195 2021-12-16 Buy
Ambeed A321287 Tris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis 1g $195 2021-12-16 Buy
Ambeed A318556 Tris(triphenylphosphine)chlororhodium 98% 5g $748 2021-12-16 Buy
Ambeed A321287 Tris(triphenylphosphine)chlororhodium 99.9%tracemetalsbasis 5g $748 2021-12-16 Buy
American Custom Chemicals Corporation ING0025886 TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE 95.00% 1G $154.35 2021-12-16 Buy
Arctom SY007812 Tris(triphenylphosphine)rhodium(I) Chloride 11% 250mg $70 2021-12-16 Buy
Arctom SY007812 Tris(triphenylphosphine)rhodium(I) Chloride 11% 1g $230 2021-12-16 Buy

Properties

Melting point :245-250 °C (dec.)
Boiling point :>170°C
Density :1.363; d 1.379
vapor pressure :0Pa at 25℃
storage temp. :Keep in dark place,Inert atmosphere,Room temperature
solubility :Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form :Crystalline Powder
color :Red-brown to maroon
Water Solubility :insoluble
Sensitive :air sensitive
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
Merck :14,9758
BRN :4581440
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 InChIKey :QEYYHUJFSQCTAE-UHFFFAOYSA-M
LogP :5.69 at 20℃
CAS DataBase Reference :14694-95-2(CAS DataBase Reference)
NIST Chemistry Reference :chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA Substance Registry System :Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.

Description

Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes.