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ChemicalBook >> CAS DataBase List >> BUTYLZINC BROMIDE

BUTYLZINC BROMIDE

BUTYLZINC BROMIDE price.
  • $80 - $3688
  • Product name: BUTYLZINC BROMIDE
  • CAS: 92273-73-9
  • MF: C4H9BrZn
  • MW: 202.4
  • EINECS:
  • MDL Number:MFCD00671997
  • Synonyms:BUTYLZINC BROMIDE, 0.5M SOLUTION IN TETR AHYDROFURAN;butylzinc bromide solution;N-BUTYLZINC BROMIDE;BUTYLZINC BROMIDE;n-Butylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;Butylzinc bromide solution 0.5 in THF;Zinc, bromobutyl-;Butylzinc bromide, 0.50 M in THF
11 prices
Selected condition:
Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Matrix Scientific
  • Oakwood
  • Rieke Metals
  • Sigma-Aldrich
Package
  • 5ml
  • 50ml
  • 100ML
  • 500ML
  • 1L
  • ManufacturerAlfa Aesar
  • Product numberH58121
  • Product descriptionn-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
  • Packaging50ml
  • Price$189.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0006324
  • Product descriptionBUTYLZINC BROMIDE 95.00%
  • Packaging50ML
  • Price$835
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0006324
  • Product descriptionBUTYLZINC BROMIDE 95.00%
  • Packaging100ML
  • Price$1046
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0006324
  • Product descriptionBUTYLZINC BROMIDE 95.00%
  • Packaging500ML
  • Price$2044
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0006324
  • Product descriptionBUTYLZINC BROMIDE 95.00%
  • Packaging1L
  • Price$3688
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121881
  • Product descriptionButylzincbromide 0.50MinTHF97%
  • Packaging50ml
  • Price$435
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121881
  • Product descriptionButylzincbromide 0.50MinTHF97%
  • Packaging100ml
  • Price$646
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121881
  • Product descriptionButylzincbromide 0.50MinTHF97%
  • Packaging500ml
  • Price$1644
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number213843
  • Product descriptionn-Butylzincbromide0.5MinTetrahydrofuran
  • Packaging5ml
  • Price$80
  • Updated2021-12-16
  • Buy
  • ManufacturerRieke Metals
  • Product number2433
  • Product descriptionn-Butylzincbromide
  • Packaging50mL
  • Price$290
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number497746
  • Product descriptionButylzinc bromide solution 0.5 M in THF
  • Packaging50ml
  • Price$323
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar H58121 n-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles 50ml $189.65 2024-03-01 Buy
American Custom Chemicals Corporation ING0006324 BUTYLZINC BROMIDE 95.00% 50ML $835 2021-12-16 Buy
American Custom Chemicals Corporation ING0006324 BUTYLZINC BROMIDE 95.00% 100ML $1046 2021-12-16 Buy
American Custom Chemicals Corporation ING0006324 BUTYLZINC BROMIDE 95.00% 500ML $2044 2021-12-16 Buy
American Custom Chemicals Corporation ING0006324 BUTYLZINC BROMIDE 95.00% 1L $3688 2021-12-16 Buy
Matrix Scientific 121881 Butylzincbromide 0.50MinTHF97% 50ml $435 2021-12-16 Buy
Matrix Scientific 121881 Butylzincbromide 0.50MinTHF97% 100ml $646 2021-12-16 Buy
Matrix Scientific 121881 Butylzincbromide 0.50MinTHF97% 500ml $1644 2021-12-16 Buy
Oakwood 213843 n-Butylzincbromide0.5MinTetrahydrofuran 5ml $80 2021-12-16 Buy
Rieke Metals 2433 n-Butylzincbromide 50mL $290 2021-12-16 Buy
Sigma-Aldrich 497746 Butylzinc bromide solution 0.5 M in THF 50ml $323 2024-03-01 Buy

Properties

Density :0.958 g/mL at 25 °C
Flash point :1 °F
storage temp. :2-8°C
Water Solubility :Reacts with water.
Sensitive :Air Sensitive
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

Butylzinc bromide is an organozinc compound, which can be used as a reagent:
  • In palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bond by reacting with organic halides or triflates.
  • To prepare n-butylanisole by treating with 4-bromoanisole in the presence of a tetraphosphine ligand and a palladium catalyst.


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