1,2-DIMETHYLCYCLOHEXANE synthesis
- Product Name:1,2-DIMETHYLCYCLOHEXANE
- CAS Number:583-57-3
- Molecular formula:C8H16
- Molecular Weight:112.21
95-47-6
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583-57-3
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Yield:583-57-3 99%
Reaction Conditions:
with hydrogen in water at 100; under 15001.5 Torr; for 5 h;
Steps:
3.2. Hydrogenation reaction in aqueous phase
General procedure: The catalytic hydrogenation of Ru/CN-SBA-15 for olefins, arenesand the other biomass-derived platform molecules has been demonstratedin Table 3. Both alicyclic olefin and linear olefin (cyclohexeneand 1-hexene) were highly reactive over the present catalyst under the aqueous and much more mild conditions, and even TOFs were over10,000 h-1 (Table 3, entries 1 and 2). Moreover, the styrene was hydrogenatedsmoothly into ethylcyclohexane in 99% yield even under areaction condition of 60 °C and TOF reached up to 8273 h-1 (Table 3,entry 3). Similarly, the other arenes like phenylacetylene, toluene ando-xylene were also converted into the corresponding totally hydrogenatedproducts respectively, although the complete hydrogenation ofthese substrate molecules could require slightly longer reaction time orhigher temperature due to the electron-withdrawing substituent or thesteric hindrance (Table 3, entries 4-6).
References:
Qian, Wei;Lin, Lina;Qiao, Yunxiang;Zhao;Xu, Zichen;Gong, Honghui;Li;Chen;Huang, Rong;Hou, Zhenshan [Applied Catalysis A: General,2019,vol. 585,art. no. 117183]
1674-10-8
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1759-64-4
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5715-23-1
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