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ChemicalBook CAS DataBase List 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
16591-56-3

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE synthesis

6synthesis methods
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Yield: 100%

Reaction Conditions:

in toluenebyproducts: H2; cocondensation of iron and toluene vapor at liq. nitrogen temp.; heating to -94.6°C; dropwise addn. of porphine soln. under nitrogen to the slurry (molar ratio Fe:porphine 4:1); gradually warming to 0°C, 1h; filtration; evapn. of filtrate;

References:

Reagen, William K.;Radonovich, Lewis J. [Journal of the American Chemical Society,1987,vol. 109,p. 5274 - 5275]

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