(1R,2R)-2-methylcyclopropane-1-carbaldehyde synthesis
- Product Name:(1R,2R)-2-methylcyclopropane-1-carbaldehyde
- CAS Number:1226589-78-1
- Molecular formula:C5H8O
- Molecular Weight:84.12
31930-41-3
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394735-00-3
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1226589-78-1
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397266-17-0
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Yield:22 % ee
Reaction Conditions:
with wild-type 12-oxophytodienoicacid reductase 3 from Solanum lycopersicum Y190F mutant;NADH in aq. phosphate buffer;N,N-dimethyl-formamide at 25; pH=7.5; for 3 h;Darkness;Inert atmosphere;Schlenk technique;Enzymatic reaction;Reagent/catalyst;
References:
Heckenbichler, Kathrin;Schweiger, Anna;Brandner, Lea Alexandra;Binter, Alexandra;Toplak, Marina;Macheroux, Peter;Gruber, Karl;Breinbauer, Rolf [Angewandte Chemie - International Edition,2018,vol. 57,# 24,p. 7240 - 7244][Angew. Chem.,2018,# 130,p. 7360 - 7364,5] Location in patent:supporting information
![[(1R,2R)-2-METHYLCYCLOPROPYL]METHANOL](/CAS/20200119/GIF/152518-89-3.gif)
152518-89-3
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1226589-78-1
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10487-86-2
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$160.00/500mg
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