ChemicalBook CAS DataBase List 2,3,4,5,6-PENTAKISTRIFLUOROMETHYLPHENOL

2,3,4,5,6-PENTAKISTRIFLUOROMETHYLPHENOL synthesis

2synthesis methods

Product Name:2,3,4,5,6-PENTAKISTRIFLUOROMETHYLPHENOL
CAS Number:723294-91-5
Molecular formula:C11HF15O
Molecular Weight:434.1

608-74-2
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81290-20-2 Synthesis

81290-20-2
399 suppliers
$13.00/1g

Benzene,1,2,3,4,5,6-hexakis(trifluoromethyl)-

2340-93-4
1 suppliers
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723294-91-5
15 suppliers
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Benzene, 1,2,3,4,5-pentakis(trifluoromethyl)-

53812-60-5
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Yield:2340-93-4 45% ，723294-91-5 20% ，53812-60-5 14%

Reaction Conditions:

Stage #1: (trifluoromethyl)trimethylsilanewith 1,3-dimethyl-2-imidazolidinone;potassium fluoride;copper(I) bromide in N,N-dimethyl-formamide at 0;
Stage #2: hexaiodobenzene in N,N-dimethyl-formamide at 0 - 20; for 24 h;Further stages.;

References:

Kuett, Agnes;Movchun, Valeria;Rodima, Toomas;Dansauer, Timo;Rusanov, Eduard B.;Leito, Ivo;Kaljurand, Ivari;Koppel, Juta;Pihl, Viljar;Koppel, Ivar;Ovsjannikov, Gea;Toom, Lauri;Mishima, Masaaki;Medebielle, Maurice;Lork, Enno;Roeschenthaler, Gerd-Volker;Koppel, Ilmar A.;Kolomeitsev, Alexander A. [Journal of Organic Chemistry,2008,vol. 73,# 7,p. 2607 - 2620]

Benzene, 1-chloro-2,3,4,5,6-pentakis(trifluoromethyl)-

1018330-39-6
3 suppliers
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723294-91-5
15 suppliers
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References