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ChemicalBook CAS DataBase List 2-bromo-dibenzofuran-3-ylamine
83660-06-4

2-bromo-dibenzofuran-3-ylamine synthesis

4synthesis methods
-

Yield:83660-06-4 69.8%

Reaction Conditions:

with NBS in chloroform at 0 - 20;

Steps:

16.2 Step 2: Preparation of 2-bromo-dibenzo[b,d]furan-3-amine (16b)

Dibenzo[b,d]furan-3-amine (16a) (400 mg, 2.19 mmol) was dissolved in CHCl3 (20 mL) at room temperature. NBS (389 mg, 2.19 mmol) was added at 0 °C, followed by stirring at room temperature overnight. The reaction solution was concentrated under reduced pressure, and the residue was separated and purified by silica gel column chromatography (mobile phase: petroleum ether/ethyl acetate=10:1) to obtain 400 mg of the title product as a yellow solid, yield: 69.8%.

References:

WO2022/143489,2022,A1 Location in patent:Page/Page column 49; 50