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ChemicalBook CAS DataBase List (2E)-4-[2-Nitro-3-[(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy]phenyl]-4-oxo-2-butenoic Acid Methyl Ester

(2E)-4-[2-Nitro-3-[(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy]phenyl]-4-oxo-2-butenoic Acid Methyl Ester synthesis

2synthesis methods
224044-67-1 Synthesis
(2E)-4-(3-Hydroxy-2-nitrophenyl)-4-oxo-2-butenoic Acid Methyl Ester

224044-67-1
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(2E)-4-[2-Nitro-3-[(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy]phenyl]-4-oxo-2-butenoic Acid Methyl Ester

224044-68-2
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Yield:224044-68-2 61%

Reaction Conditions:

with mercury(II) cyanide;potassium carbonate in acetonitrile; for 4 h;Ambient temperature;

References:

Manthey, Michael K.;Jamie, Joanne F.;Truscott, Roger J. W. [Journal of Organic Chemistry,1999,vol. 64,# 11,p. 3930 - 3933]

93367-77-2 Synthesis
2-Butenoic acid, 4-(3-hydroxy-2-nitrophenyl)-4-oxo-

93367-77-2
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(2E)-4-[2-Nitro-3-[(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxy]phenyl]-4-oxo-2-butenoic Acid Methyl Ester

224044-68-2
9 suppliers
inquiry