2-[4-(2-Ethyl-hexyloxy)-phenyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane synthesis
- Product Name:2-[4-(2-Ethyl-hexyloxy)-phenyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
- CAS Number:251566-01-5
- Molecular formula:C20H33BO3
- Molecular Weight:332.29
61676-62-8
328 suppliers
$11.19/5G
![1-Bromo-4-[(2-ethylhexyl)oxy]benzene](/CAS/GIF/164352-24-3.gif)
164352-24-3
16 suppliers
$27.00/250mg
251566-01-5
19 suppliers
$45.00/50mg
Yield:251566-01-5 92%
Reaction Conditions:
Stage #1: 1-bromo-4-(2′-ethylhexyloxy)benzenewith n-butyllithium in tetrahydrofuran;hexane at -78; for 1 h;Inert atmosphere;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran;hexane at -78 - 20;Inert atmosphere;
References:
Song, Bok Joo;Song, Hae Min;Choi, In Taek;Kim, Sang Kyun;Seo, Kang Duk;Kang, Min Soo;Lee, Myung Jun;Cho, Dae Won;Ju, Myung Jong;Kim, Hwan Kyu [Chemistry - A European Journal,2011,vol. 17,# 40,p. 11115 - 11121] Location in patent:supporting information; experimental part
76347-13-2
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$17.00/1g
164352-24-3
16 suppliers
$27.00/250mg
251566-01-5
19 suppliers
$45.00/50mg
73183-34-3
593 suppliers
$6.00/5g
164352-24-3
16 suppliers
$27.00/250mg
251566-01-5
19 suppliers
$45.00/50mg
18908-66-2
298 suppliers
$5.00/25g
251566-01-5
19 suppliers
$45.00/50mg
106-41-2
501 suppliers
$13.00/5g
251566-01-5
19 suppliers
$45.00/50mg