Carbamic acid, (1-methyl-2-propenyl)-, 1,1-dimethylethyl ester (9CI) synthesis
- Product Name:Carbamic acid, (1-methyl-2-propenyl)-, 1,1-dimethylethyl ester (9CI)
- CAS Number:267668-37-1
- Molecular formula:C9H17NO2
- Molecular Weight:171.24
598-32-3
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216959-34-1
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$22.00/100mg
267668-37-1
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Yield:267668-37-1 63%
Reaction Conditions:
Stage #1: 2-hydroxy-3-butene;ethyl 2-{[(tert-butoxy)carbonyl]amino}-2-oxoacetatewith di-isopropyl azodicarboxylate;triphenylphosphine in tetrahydrofuran at 0 - 20;Inert atmosphere;Mitsunobu Displacement;
Stage #2: with lithium hydroxide in tetrahydrofuran;water at 20;Inert atmosphere;regioselective reaction;Reagent/catalyst;
References:
Van Veen, Branca C.;Wales, Steven M.;Clayden, Jonathan [Journal of Organic Chemistry,2021,vol. 86,# 12,p. 8538 - 8543]
1070-19-5
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267668-37-1
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1826-67-1
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$60.89/100ml
![Carbamic acid, N-[1-[(4-methylphenyl)sulfonyl]ethyl]-, 1,1-dimethylethyl ester](/CAS/20200611/GIF/365441-85-6.gif)
365441-85-6
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267668-37-1
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