3-(2,4,5-TRIMETHYLPHENYL)-1-PROPENE synthesis
- Product Name:3-(2,4,5-TRIMETHYLPHENYL)-1-PROPENE
- CAS Number:58474-27-4
- Molecular formula:C12H16
- Molecular Weight:160.26
824-45-3
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$13.00/500mg
2551-83-9
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$6.00/1g
58474-27-4
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$252.00/1g
Yield:58474-27-4 77%
Reaction Conditions:
Stage #1: 2,5-dimethylbenzyl chloride;allyltrimethoxysilanewith tetrakis(triphenylphosphine) palladium(0);tetrabutyl ammonium fluoride in tetrahydrofuran;dichloromethane at 20; for 18 h;Inert atmosphere;Hiyama Coupling;
Stage #2: with toluene-4-sulfonic acid in tetrahydrofuran;dichloromethane at 20; for 0.166667 h;Inert atmosphere;regioselective reaction;
References:
Zhang, Sheng;Cai, Jinfang;Yamamoto, Yoshinori;Bao, Ming [Journal of Organic Chemistry,2017,vol. 82,# 11,p. 5974 - 5980]
6626-30-8
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58474-27-4
11 suppliers
$252.00/1g