3,3''-DIBROMO-4,4''-DIMETHOXYBIPHENYL synthesis
- Product Name:3,3''-DIBROMO-4,4''-DIMETHOXYBIPHENYL
- CAS Number:108989-36-2
- Molecular formula:C14H12Br2O2
- Molecular Weight:372.05
2132-80-1
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108989-36-2
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Yield: 90%
Reaction Conditions:
with N-Bromosuccinimide in acetonitrile for 5 h;Reflux;
Steps:
A representative synthetic procedure of compounds 7 and 8 is as follows
NBS (for 7, 428 mg, 2.4 mmol; for 8, 783 mg, 4.4 mmol) was added to a solution of compound 2 (430 mg, 2.0 mmol) in MeCN (10 mL) at rt. The reaction mixture was stirred at reflux for 5 h. The reaction mixture was concentrated to yield the residue. The residue was extracted with EtOAc (3×30 mL). The combined organic layers were washed with brine, dried, filtered, and evaporated to afford crude product. Purification on silica gel (hexanes/EtOAc=10/1-6/1) afforded compound 7 or 8.
References:
Chang, Meng-Yang;Lee, Tein-Wei;Lin, Shin-Ying [Tetrahedron,2013,vol. 69,# 1,p. 228 - 234]
2132-80-1
96 suppliers
$11.00/5g
108989-36-2
38 suppliers
$45.00/50mg
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
1000210-73-0
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578-57-4
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$6.00/10g
108989-36-2
38 suppliers
$45.00/50mg