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ChemicalBook CAS DataBase List 4-(cyclopropylmethoxy)aniline
122828-48-2

4-(cyclopropylmethoxy)aniline synthesis

2synthesis methods
-

Yield:122828-48-2 99%

Reaction Conditions:

with hydrogen;palladium 10% on activated carbon in ethyl acetate at 20; under 2327.23 Torr; for 2 h;

Steps:



1-(cyclopropylmethoxy)-4-nitrobenzene (1.24 g, 6.418 mmol) in ethyl acetate (40 mL) was added 10% palladium on acivated carbon (50 mg) and allowed to stir in a parr shaker at room temperature under hydrogen (45 PSI) for 2 hours. Reaction mixture was carefully filtered through a pad of celite under a steady stream of nitrogen washing with ethyl acetate. Filtrate concentrated to give 4-(cyclopropylmethoxy)benzenamine (1.04 g, 99%) as a colorless oil, which was used for the next step without further purification.

References:

US2010/197591,2010,A1 Location in patent:Page/Page column 43