ChemicalBook CAS DataBase List (1R)-1,2,6,7,8,8a-Hexahydro-1,8aα-dimethyl-7β-(1-methylethenyl)naphthalene

(1R)-1,2,6,7,8,8a-Hexahydro-1,8aα-dimethyl-7β-(1-methylethenyl)naphthalene synthesis

2synthesis methods

Product Name:(1R)-1,2,6,7,8,8a-Hexahydro-1,8aα-dimethyl-7β-(1-methylethenyl)naphthalene
CAS Number:5090-61-9
Molecular formula:C15H22
Molecular Weight:202.34

4674-50-4 Synthesis

4674-50-4
278 suppliers
$25.00/50mg

(1R)-1,2,6,7,8,8a-Hexahydro-1,8aα-dimethyl-7β-(1-methylethenyl)naphthalene

5090-61-9
0 suppliers
inquiry

Yield: 56%

Reaction Conditions:

Stage #1:(+)-nootkatone with C₁₉H₂₆ClIrN₃O⁽¹⁺⁾*Cl^(1-) in water;acetonitrile at 80; for 0.166667 h;Green chemistry;
Stage #2: with formic acid in water;acetonitrile at 80; for 4 h;Green chemistry;regioselective reaction;

References:

Li, Jide;Tang, Weiping;Ren, Demin;Xu, Jiaxi;Yang, Zhanhui [Green Chemistry,2019,vol. 21,# 8,p. 2088 - 2094] Location in patent:supporting information

Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-

1000210-73-0
0 suppliers
inquiry

5090-61-9
0 suppliers
inquiry

References