ChemicalBook CAS DataBase List DIHYDROEUGENOL

DIHYDROEUGENOL synthesis

13synthesis methods

Product Name:DIHYDROEUGENOL
CAS Number:2785-87-7
Molecular formula:C10H14O2
Molecular Weight:166.22

By catalytic reduction of eugenol with a palladium- or platinum-black catalyst.

97-54-1 Synthesis

97-54-1
401 suppliers
$6.00/10g

2785-87-7
122 suppliers
$22.12/25G

Yield:2785-87-7 98%

Reaction Conditions:

with hydrogen in methanol at 20; for 20 h;chemoselective reaction;

Steps:

4.3. Typical procedure for the chemoselective hydrogenation
General procedure: The mixture of the substrate (0.250 mmol), 0.5% Pd/MS3A or 0.5% Pd/MS5A (10 wt % of the substrate) and MeOH (1 mL) was stirred under H₂ atmosphere (balloon) at room temperature. After a given period, the reaction mixture was filtered through a membrane filter (Millipore, Millex-LH, 0.45 mm), and the filtrate was concentrated in vacuo to produce the corresponding reduced product.

References:

Takahashi, Tohru;Yoshimura, Masatoshi;Suzuka, Hiroyasu;Maegawa, Tomohiro;Sawama, Yoshinari;Monguchi, Yasunari;Sajiki, Hironao [Tetrahedron,2012,vol. 68,# 39,p. 8293 - 8299] Location in patent:experimental part

97-53-0 Synthesis