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ChemicalBook CAS DataBase List Methyl 4-(4-chlorophenyl)-3-oxobutanoate
1048916-89-7

Methyl 4-(4-chlorophenyl)-3-oxobutanoate synthesis

2synthesis methods
25026-34-0 Synthesis
4-Chlorobenzeneacetyl chloride

25026-34-0
150 suppliers
$15.00/1g

Methyl 4-(4-chlorophenyl)-3-oxobutanoate

1048916-89-7
7 suppliers
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Yield:1048916-89-7 34%

Reaction Conditions:

Stage #1: acetic acid methyl esterwith lithium diisopropyl amide in tetrahydrofuran;Inert atmosphere;Cooling;
Stage #2: 4-chlorophenacetyl chloride in tetrahydrofuran at -78 - 20;Inert atmosphere;

References:

Adeel, Muhammad;Rashid, Muhammad A.;Rasool, Nasir;Ahmad, Rasheed;Villinger, Alexander;Reinke, Helmut;Fischer, Christine;Langer, Peter [Synthesis,2009,# 2,p. 243 - 250] Location in patent:experimental part