(PERFLUOROHEPTANOYL)ACETONE synthesis
3synthesis methods
- Product Name:(PERFLUOROHEPTANOYL)ACETONE
- CAS Number:82822-26-2
- Molecular formula:C10H5F13O2
- Molecular Weight:404.12
Yield:82822-26-2 70%
Reaction Conditions:
Stage #1: methyl perfluoroheptanoatewith sodium methylate in methanol;diethyl ether at 0; for 0.5 h;
Stage #2: acetone in methanol;diethyl ether at 20; for 16 h;Further stages.;Claisen condensation;
References:
Büttner, Stefan;Lubbe, Mathias;Reinke, Helmut;Fischer, Christine;Langer, Peter [Tetrahedron,2008,vol. 64,# 34,p. 7968 - 7976]
