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ChemicalBook CAS DataBase List (R)-2-(4-nitrophenyl)propanoic acid
142927-07-9

(R)-2-(4-nitrophenyl)propanoic acid synthesis

4synthesis methods
201230-82-2 Synthesis
carbon monoxide

201230-82-2
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(S)-2-(4-nitrophenyl)propanoic acid

142927-08-0
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(R)-2-(4-nitrophenyl)propanoic acid

142927-07-9
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Yield:88 % ee

Reaction Conditions:

with water;hydrogen iodide;C52H52NO3P;palladium dichloride in tetrahydrofuran at 20; under 34202.3 Torr; for 72 h;Autoclave;Overall yield = 61 percent; enantioselective reaction;

References:

Guan, Zheng-Hui;Ren, Zhi-Hui;Wang, Yuan;Yang, Hui-Yi;Yao, Ya-Hong;Zou, Xian-Jin [Angewandte Chemie - International Edition,2021,vol. 60,# 43,p. 23117 - 23122][Angew. Chem.,2021,vol. 133,# 43,p. 23301 - 23306] Location in patent:supporting information