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RARECHEM AQ BD AN06 synthesis

5synthesis methods
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Yield:23674-17-1 71%

Reaction Conditions:

Stage #1: 9,10-Dibromoanthracenewith n-butyllithium in diethyl ether;hexane at 0; for 1 h;Inert atmosphere;
Stage #2: methyl iodide in tetrahydrofuran;diethyl ether;hexane at 20; for 1 h;Inert atmosphere;

References:

Christensen, Peter R.;Patrick, Brian O.;Caron, Elise;Wolf, Michael O. [Angewandte Chemie - International Edition,2013,vol. 52,# 49,p. 12946 - 12950][Angew. Chem.,2013,vol. 125,# 49,p. 13184 - 13188,5] Location in patent:supporting information