RHENIUM PENTACARBONYL CHLORIDE synthesis
- Product Name:RHENIUM PENTACARBONYL CHLORIDE
- CAS Number:14099-01-5
- Molecular formula:C5ClO5Re
- Molecular Weight:361.71
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14099-01-5
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Yield:14099-01-5 68%
Reaction Conditions:
in dichloromethane
Steps:
Synthesis ofRe(CO)5Cl:
A mixture of dirhenium decacarbonyl, Re(CO)io (1.90 g, 2.91 mmol) and DCM (20 mL) was stirred until Re(CO)io was completely dissolved. Then iodobenzene dichloride (0.711 g, 2.59 mmol) was added to the mixture and stirred for 45 minutes to 1 hour. A white precipitate formed, which was filtered and washed with hexanes (-20-30 mL). The resulting filtrate was allowed to stir for an additional 4-5 hours to allow further precipitation of Re(CO)5Cl. Yield: 1.268 g (68%). IR (KBr, cm"1): 3435 w, 2462 w, 21567 m, 2035 s, 1958 s, 1002 w, 942 w, 912 w, 590 s, and 555 s.
References:
CORNELL UNIVERSITY;WILSON, Justin;KNOPF, Kevin;MARKER, Sierra WO2017/223428, 2017, A1 Location in patent:Paragraph 0066
14285-68-8
74 suppliers
$24.00/100mg
14099-01-5
55 suppliers
$39.00/100mg
14524-92-6
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14099-01-5
55 suppliers
$39.00/100mg