(Z)-3-(Tributylstannyl)prop-2-en-1-ol synthesis
- Product Name:(Z)-3-(Tributylstannyl)prop-2-en-1-ol
- CAS Number:74141-12-1
- Molecular formula:C15H32OSn
- Molecular Weight:347.12
Yield:74141-12-1 67%
Reaction Conditions:
with lithium aluminium tetrahydride;ammonia;ammonium chloride in tetrahydrofuran;diethyl ether;(Ar); addn. of alcohol to a suspn. of LiAlH4 in THF at 0°C, stirring for 17 h at room temp., addn. of a soln. of tin compd. in Et2O at -60°C, stirring for 4 h, bubbling NH3; addn. of methanol, aq. NH4Cl satd. with NH3, hexane, filtration with Celite, evapn., extn. with hexane, drying with MgSO4, evapn.;
References:
Nishida, Takuma;Watanabe, Saisuke;Yoshida, Tomohiro;Ogoshi, Sensuke;Murahashi, Tetsuro;Kurosawa, Hideo [Journal of Organometallic Chemistry,2001,vol. 625,# 1,p. 54 - 57]
![Stannane, tributyl[(1Z)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-propen-1-yl]-](/CAS/20210305/GIF/86646-19-7.gif)
86646-19-7
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74141-12-1
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