ChemicalBook CAS DataBase List (Z)-8-DODECEN-1-YL ACETATE

(Z)-8-DODECEN-1-YL ACETATE synthesis

11synthesis methods

Product Name:(Z)-8-DODECEN-1-YL ACETATE
CAS Number:28079-04-1
Molecular formula:C14H26O2
Molecular Weight:226.35

153123-34-3
0 suppliers
inquiry

108-24-7
5 suppliers
$14.00/250ML

28079-04-1
127 suppliers
inquiry

Yield:28079-04-1 95%

Reaction Conditions:

with pyridine at 5 - 25; for 2 h;Large scale;

Steps:

1.d ( Z/ Ε) -8-dodecene acetate

Synthesis of Z / E-8-dodecene enol (1.1kg, 6mol) and pyridine (31) were added to the reaction Kettle, cooled to 5-10 ° (after, add acetic anhydride (1.22kg, 12mol), naturally raise to room temperature 20-25 ° C to the end of the reaction; slowly add ice water to make the temperature <10 ° C, plus After stirring for 2 hours, extracted with n-hexane three times, with sulfuric acid to adjust the PH value of 1, and then Na2C03 washed to neutral, dry And the product was distilled under reduced pressure. (Z / Ε) -8-dodecene acetate 1.3kg, The yield of 95%, by GCMS test crossover ratio of 98:2.

References:

CN104177256,2016,B Location in patent:Paragraph 0037; 0038

40642-40-8 Synthesis