ChemicalBook--->CAS DataBase List--->119-94-8

119-94-8

119-94-8 Structure

119-94-8 Structure
IdentificationMore
[Name]

Ethylbenzyltoluidine
[CAS]

119-94-8
[Synonyms]

ethylbenzyltoluidine
N-BENZYL-N-ETHYL-M-TOLUIDINE
n-ethyl-n-(3-methyl phenyl)-benzenemethanamine
N-ETHYL-N-BENZYL-M-TOLUIDINE
N-ETHYL-N-(M-TOLYL)BENZYLAMINE
3-(N-Benzyl-N-ethylamino)methylbenzene
3-(N-Benzyl-N-ethylamino)toluene
Benzenemethanamine, N-ethyl-N-(3-methylphenyl)-
m-Toluidine, N-benzyl-N-ethyl-
N-Benzyl-N-ethyl-3-methylaniline
N-Benzyl-N-ethyl-meta-toluidine
n-ethyl-n-(3-methylphenyl)-benzenemethanamin
N-Ethyl-N-benzyl-meta-toluidine
N-ethyl-N-benzyl-3-methylaniline
n-ethyl-n-benzyl-m-toluidine(ebmt)
N-BENZYL-N-ETHYL-3-TOLUIDINE
Ethylbenzyl-m-toluidine
N-Ethyl-N-benzyl-m-toluidin
N-Ethyl-3-methyl-N-(phenylmethyl)aniline
[EINECS(EC#)]

204-359-6
[Molecular Formula]

C16H19N
[MDL Number]

MFCD00025950
[Molecular Weight]

225.33
[MOL File]

119-94-8.mol
Chemical PropertiesBack Directory
[Boiling point ]

161-162 °C(lit.)
[density ]

0.770 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.5870(lit.)
[Fp ]

171 °F
[storage temp. ]

Sealed in dry,2-8°C
[form ]

Liquid
[pka]

5.40±0.50(Predicted)
[CAS DataBase Reference]

119-94-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenemethanamine, n-ethyl-n-(3-methylphenyl)-(119-94-8)
[EPA Substance Registry System]

119-94-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2753 6.1/PG 3
[WGK Germany ]

2
[TSCA ]

Yes
[HazardClass ]

6.1
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Acid Blue 90-->Benzenemethanaminium, N-ethyl-N-[4-[[4-[ethyl[(3-sulfophenyl)methyl]amino]phenyl][4-(phenylamino)phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-3-sulfo-, inner salt, sodium salt (1:1)-->Acid Blue 90-->N-Ethyl-N-[4-[[4-[N-ethyl-N-(3-sodiosulfobenzyl)amino]-2-methylphenyl][4-[[2-(phenylamino)phenyl]amino]phenyl]methylene]-3-methyl-2,5-cyclohexadien-1-ylidene]-3-sulfonatobenzenemethanaminium-->Benzenemethanaminium,N-ethyl-N-[4-[[4-[ethyl[(3-sulfophenyl)methyl]amino]-2-methylphenyl][4-(phenylamino)phenyl]methylene]-3-methyl-2,5-cyclohexadien-1-ylidene]-3-sulfo-,inner salt, sodium salt (1:1)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ethylbenzyltoluidine(119-94-8).msds
Hazard InformationBack Directory
[Description]

Ethylbenzyltoluidine is a yellowish to lightbrown liquid with an unpleasant odor. Boilingpoint = 230℃; Flash point = 167℃. Insoluble in water.
[Chemical Properties]

Yellow - light brown liquid.
[Uses]

Ethylbenzyltoluidine can be used as an intermediate for acid blue 90, 91, 109 and other dyes.
[Synthesis]

The ratio of N-ethyl-m-toluidine to benzyl chloride is 1: (0.95~1.05) (molar ratio), and Ethylbenzyltoluidine can be obtained after reaction.
[Potential Exposure]

This compound is used in dyesynthesis
[First aid]

Eye Contact: Immediately remove any contactlenses and flush with large amounts of water for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately.Skin Contact: Quickly remove contaminated clothing.Immediately wash area with large amounts of soap andwater. Seek medical attention if symptoms develop andremove the person from exposure. Begin rescue breathing(using universal precautions, including resuscitation mask)if breathing has stopped and CPR if heart action hasstopped. Transfer promptly to a medical facility.Note to physician: Treat for methemoglobinemia.Spectrophotometry may be required for precise determination of levels of methemoglobinemia in urine.
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers and light. Where possible, automatically pump liquid from drums or other storagecontainers to process containers
[Shipping]

This compound requires a shipping label of“POISONOUS/TOXIC MATERIALS.” It falls in HazardClass 6.1 and Packing Group III.
[Incompatibilities]

Strong oxidizers.
[Short Term Exposure]

Exposure can interfere with the ability of the blood to carry oxygen (methemoglobinemia),causing headaches, dizziness, weakness, a bluish skin color,and even death. This substance can damage the kidneys andbladder, causing painful, bloody urine. Eye contact causesirritation and can lead to permanent damage. Skin contactcan cause a rash and burning feeling
[Personal Protective Methods]

Wear protective gloves andclothing to prevent any reasonable probability of skin contact. Safety equipment suppliers/manufacturers can providerecommendations on the most protective glove/clothingmaterial for your operation. All protective clothing (suits,gloves, footwear, headgear) should be clean, available eachday, and put on before work. Contact lenses should not beworn when working with this chemical. Wear splash-proofchemical goggles and face shield unless full face-piecerespiratory protection is worn. Employees should washimmediately with soap when skin is wet or contaminated.Provide emergency showers and eyewash
[Fire Extinguishing]

Ethylbenzyltoluidine may burn butdoes not readily ignite. Poisonous gases are produced infire. Use dry chemical, carbon dioxide, or alcohol foamextinguishers. Vapors in confined areas may explode whenexposed to fire. Containers may explode in fire. Storagecontainers and parts of containers may rocket great distances, in many directions. If material or contaminated runoff enters waterways, notify downstream users ofpotentially contaminated waters. Notify local health and fireofficials and pollution control agencies. From a secure,explosion-proof location, use water spray to cool exposedcontainers. If cooling streams are ineffective (venting soundincreases in volume and pitch, tank discolors, or shows anysigns of deforming), withdraw immediately to a secure position. If employees are expected to fight fires, they must betrained and equipped in OSHA 1910.156. The only respirators recommended for firefighting are self-contained breathing apparatuses that have full face-pieces and are operatedin a pressure-demand or other positive-pressure mode.
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

119-94-8(sigmaaldrich)
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