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1570-64-5

1570-64-5 Structure

1570-64-5 Structure
IdentificationMore
[Name]

4-Chloro-2-methylphenol
[CAS]

1570-64-5
[Synonyms]

2-METHYL-4-CHLOROPHENOL
4-CHLORO-2-CRESOL
4-CHLORO-2-METHYLPHENOL
4-CHLORO-O-CRESOL
5-CHLORO-2-HYDROXYTOLUENE
4-chloro-2-methyl-pheno
4-chloro-o-creso
ai3-24520
o-Cresol, 4-chloro-
para-chloro-ortho-cresol
p-Chloro-o-cresol
4-CHLORO-2-METHYLPHENOL, 1GM, NEAT
4-CHLORO-2-METHYLPHENOL, 1000MG, NEAT
4-Chloro-o-methylphenol
Phenol, 4-chloro-2-methyl-
4-chloro-0-cresol
4-CHLORO-ORTHO-CRESOL
4-Chlor-2-methylphenol
97-99℃
Chlorocresol (ortho-)
[EINECS(EC#)]

216-381-3
[Molecular Formula]

C7H7ClO
[MDL Number]

MFCD00002321
[Molecular Weight]

142.58
[MOL File]

1570-64-5.mol
Chemical PropertiesBack Directory
[Appearance]

Off-white to slightly brownish crystalline solid
[Melting point ]

43-46 °C(lit.)
[alpha ]

22 º (c=8,6N HCl)
[Boiling point ]

220-225 °C(lit.)
[density ]

1.20
[vapor pressure ]

26.66Pa at 19.85℃
[refractive index ]

1.5449 (estimate)
[Fp ]

>230 °F
[storage temp. ]

0-6°C
[form ]

neat
[pka]

9.87±0.18(Predicted)
[color ]

white to brown
[Water Solubility ]

<0.1 g/100 mL at 15 ºC
[BRN ]

1906684
[InChIKey]

RHPUJHQBPORFGV-UHFFFAOYSA-N
[CAS DataBase Reference]

1570-64-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Phenol, 4-chloro-2-methyl-(1570-64-5)
[EPA Substance Registry System]

1570-64-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,C,N,Xn
[Risk Statements ]

R23:Toxic by inhalation.
R35:Causes severe burns.
R50:Very Toxic to aquatic organisms.
R38:Irritating to the skin.
R21/22:Harmful in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

UN 3437 6.1/PG 2
[WGK Germany ]

2
[RTECS ]

GO7120000
[Hazard Note ]

Toxic/Corrosive
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29081990
[Hazardous Substances Data]

1570-64-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

4-CHLORO-2,6-DIMETHYLPHENOL-->2,6-DIBROMO-4-CHLOROPHENOL-->Methyllithium
[Preparation Products]

2-Methyl-4-chlorophenoxyacetic acid-->MCPB-->2,6-Dimethylphenol-->2-(4-CHLORO-2-METHYLPHENOXY)PYRIDINE-3-CARBOXYLIC ACID-->5-Chloro-2-hydroxy-3-iodotoluene
Hazard InformationBack Directory
[General Description]

Dark red flakes with waxy texture. Insoluble in water.
[Reactivity Profile]

P-CHLORO-O-CRESOL(1570-64-5) can react vigorously with concentrated sodium hydroxide solutions. Also reacts with other bases, acid chlorides, acid anhydrides, and oxidizing agents. Corrodes steel, brass, copper and copper alloys [NTP, 1992)]. A large quantity left in contact with concentrated sodium hydroxide solution for 3 days reacted violently, attaining red heat and evolving fumes that ignited explosively. The heat of reaction dissipated poorly because of the high viscosity of the mixture [Quart. Safety Summ., 1957, 28, 39].
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

This chemical is probably combustible.
[Chemical Properties]

Off-white to slightly brownish crystalline solid
[Definition]

ChEBI: A member of the class of phenols that is o-cresol in which the hydrogen para to the hydroxy group is replaced by a chlorine.
[Synthesis Reference(s)]

Tetrahedron Letters, 30, p. 5215, 1989 DOI: 10.1016/S0040-4039(01)93745-1
[Flammability and Explosibility]

Nonflammable
[Purification Methods]

Purify the phenol by crystallisation from pet ether (m 51o) and by zone melting. [Beilstein 6 H 359, 6 I 174, 6 II 332, 6 III 1264, 6 IV 1987.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Chloro-o-cresol(1570-64-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

4-Chloro-2-methylphenol(1570-64-5)MS
4-Chloro-2-methylphenol(1570-64-5)1HNMR
4-Chloro-2-methylphenol(1570-64-5)13CNMR
4-Chloro-2-methylphenol(1570-64-5)IR1
4-Chloro-2-methylphenol(1570-64-5)IR2
4-Chloro-2-methylphenol(1570-64-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Chloro-2-methylphenol, 97%(1570-64-5)
[Alfa Aesar]

4-Chloro-2-methylphenol, 97%(1570-64-5)
[Sigma Aldrich]

1570-64-5(sigmaaldrich)
[TCI AMERICA]

4-Chloro-o-cresol,>90.0%(GC)(1570-64-5)
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