ChemicalBook--->CAS DataBase List--->407-14-7

407-14-7

407-14-7 Structure

407-14-7 Structure
IdentificationMore
[Name]

1-Bromo-4-(trifluoromethoxy)benzene
[CAS]

407-14-7
[Synonyms]

1-BROMO-4-(TRIFLUOROMETHOXY)BENZENE
4-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE
4-BROMO(TRIFLUOROMETHOXY)BENZENE
4-(TRIFLUOROMETHOXY)BROMOBENZENE
P-BROMOTRIFLUOROMETHOXYBENZENE
P-TRIFLUOROMETHOXY BROMOBENZENE
TIMTEC-BB SBB006606
Benzene, 1-bromo-4-(trifluoromethoxy)-
P-Bromotrifluoromethoxybenzen
4-Bromozbenzotrifluoride
1-Bromo-4-(Trifluoromethoxy)Be
4-(Trifluoromethoxy)bromobenzene 99%
4-BROMOA-TRIFLUOROMETHOXYBENZENE
4-(Trifluoromethoxy)bromobenzene99%
1-Brom-4-(trifluormethoxy)benzol
1-Bromo-4-(trifluromethoxy)benzene
4-(trifluoromethoxy)bromobenzene,1-bromo-4-(trifluoromethoxy)benzene
p-Bromophenyl trifluoromethyl ether
4-Bromophenyl(trifluoromethyl) ether
[EINECS(EC#)]

206-979-2
[Molecular Formula]

C7H4BrF3O
[MDL Number]

MFCD00040834
[Molecular Weight]

241.01
[MOL File]

407-14-7.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO YELLOW LIQUID
[Boiling point ]

80 °C50 mm Hg(lit.)
[density ]

1.622 g/mL at 25 °C(lit.)
[vapor pressure ]

20 hPa (55 °C)
[refractive index ]

n20/D 1.461(lit.)
[Fp ]

154 °F
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

11.7mg/l
[form ]

Liquid
[color ]

Clear colorless to yellow
[Specific Gravity]

1.64
[BRN ]

2046332
[InChIKey]

SEAOBYFQWJFORM-UHFFFAOYSA-N
[CAS DataBase Reference]

407-14-7(CAS DataBase Reference)
[NIST Chemistry Reference]

P-bromophenyl trifluoromethyl ether(407-14-7)
Safety DataBack Directory
[Hazard Codes ]

Xn,N,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

1
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29093090
[Toxicity]

LD50 orally in Rabbit: > 2500 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Bromobenzene
[Preparation Products]

1-Iado-4-(trifluoromethoxy)benzene-->4-(Trifluoromethoxy)benzoic acid-->3-(Trifluoromethoxy)bromobenzene-->(4-BROMO-PHENYL)-(4-TRIFLUOROMETHOXY-PHENYL)-METHANONE-->3-[4-(TrifluoroMethoxy)phenyl]benzonitrile-->ethyl 5-bromo-2-(trifluoromethoxy)benzoate-->4-Trifluoromethoxyphenylboronic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Bromo-4-(trifluoromethoxy)benzene(407-14-7).msds
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO YELLOW LIQUID
[Uses]

1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 109, p. 3708, 1987 DOI: 10.1021/ja00246a030
[General Description]

1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene.
Spectrum DetailBack Directory
[Spectrum Detail]

1-Bromo-4-(trifluoromethoxy)benzene(407-14-7)MS
1-Bromo-4-(trifluoromethoxy)benzene(407-14-7)1HNMR
1-Bromo-4-(trifluoromethoxy)benzene(407-14-7)13CNMR
1-Bromo-4-(trifluoromethoxy)benzene(407-14-7)IR1
1-Bromo-4-(trifluoromethoxy)benzene(407-14-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Bromo-4-(trifluoromethoxy)benzene, 98%(407-14-7)
[Alfa Aesar]

1-Bromo-4-(trifluoromethoxy)benzene, 98%(407-14-7)
[Sigma Aldrich]

407-14-7(sigmaaldrich)
[TCI AMERICA]

1-Bromo-4-(trifluoromethoxy)benzene,>97.0%(GC)(407-14-7)
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