| Identification | More | [Name]
2-Fluorobenzoic acid | [CAS]
445-29-4 | [Synonyms]
2-FLUOROBENZOIC ACID
2-Fluorobenzoicaid
AKOS BBS-00003806
OFBA
O-FLUOROBENZOIC ACID
RARECHEM AL BO 0015
2-fluoro-benzoicaci
Benzoic acid, o-fluoro-
o-Fluorbenzoesaeure
o-fluoro-benzoicaci
ortho-Fluorobenzoic acid
Fluorobenzoicacidminwhitepowder
o-Fluorobenzoic Acid 2-Fluorobenzoic Acid
2-Fluorobenzoi acid
2-Fluorobenzoicacid,97%
o-Fluorobenzoicacid,min.97%
Benzoic acid, 2-fluoro-
2-Fluorobenzoicacid98%
2-FLUOROICBENZOIC ACID
2-FLUOROBENZOHYDRAZIDE | [EINECS(EC#)]
207-158-1 | [Molecular Formula]
C7H5FO2 | [MDL Number]
MFCD00002405 | [Molecular Weight]
140.11 | [MOL File]
445-29-4.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powder | [Melting point ]
122-125 °C (lit.) | [Boiling point ]
114 °C | [density ]
1,46 g/cm3 | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
7.2g/l | [form ]
Crystalline Powder or Needles | [pka]
3.27(at 25℃) | [color ]
White to light yellow | [Water Solubility ]
Slightly soluble in water. | [BRN ]
971265 | [InChI]
InChI=1S/C7H5FO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10) | [InChIKey]
NSTREUWFTAOOKS-UHFFFAOYSA-N | [SMILES]
C(O)(=O)C1=CC=CC=C1F | [CAS DataBase Reference]
445-29-4(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzoic acid, 2-fluoro-(445-29-4) | [EPA Substance Registry System]
445-29-4(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R37/38:Irritating to respiratory system and skin .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
DH0250000
| [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29163900 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powder | [Uses]
Meclofenamic Acid intermediate. | [Definition]
ChEBI: A 2-halobenzoic acid that is benzoic acid carrying a fluoro substituent at position 2. | [Preparation]
The preparation of 2-fluorobenzoic acid is based on anthranilic acid as raw material, adding anhydrous hydrogen fluoride and sodium nitrite in methoxyethyl methyl ether solvent for diazotization, refluxing for 3 hours, and post-processing to obtain the finished product. | [Purification Methods]
Crystallise the acid from 50% aqueous EtOH, dilute HCl or *C6H6, then purify it by zone melting or vacuum sublimation at 130-140o. [Beilstein 9 H 333. 9 III 1324, 9 IV 950.] |
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