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5166-67-6

5166-67-6 Structure

5166-67-6 Structure
IdentificationMore
[Name]

Ethyl 1-methylnipecotate
[CAS]

5166-67-6
[Synonyms]

1-METHYL-PIPERIDINE-3-CARBOXYLIC ACID ETHYL ESTER
ETHYL 1-METHYL-3-PIPERIDINE-CARBOXYLATE
ETHYL 1-METHYLNIPECOTATE
ETHYL 1-METHYLPIPERIDINE-3-CARBOXYLATE
LABOTEST-BB LT00159658
3-Piperidinecarboxylic acid, 1-methyl-, ethyl ester
Ethyl 1-methylpiperidine-3-carboxylate 97%
Ethyl 1-methylnipecotate, 98+%
1-Methyl-3-piperidinecarboxylic acid ethyl ester
[EINECS(EC#)]

225-951-0
[Molecular Formula]

C9H17NO2
[MDL Number]

MFCD00006496
[Molecular Weight]

171.24
[MOL File]

5166-67-6.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colorless to pale yellow liquid
[Boiling point ]

88-89 °C/11 mmHg (lit.)
[density ]

0.954 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.451(lit.)
[Fp ]

155 °F
[storage temp. ]

Sealed in dry,Room Temperature
[pka]

8.56±0.10(Predicted)
[BRN ]

123259
[CAS DataBase Reference]

5166-67-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethyl 1-methylnipecotate(5166-67-6)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[F ]

9-23
[Hazard Note ]

Irritant
[HS Code ]

29333990
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to pale yellow liquid
[Uses]

Reactant for:
N-demethylation of tertiary amines
Reverse cope elimination reactions
Regioselective oxidation
Synthesis of chelating agents
Sequential Michael-Michael-Dieckmann cyclizations
[General Description]

Enantiomeric discrimination has been investigated in 1H and 13C NMR spectra of ethyl 1-methyl-3-piperidinecarboxylate in the presence of (-)-(18-crown-6)-2,3,11,12-tetracarboxylic acid.
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl 1-methylnipecotate(5166-67-6)MS
Ethyl 1-methylnipecotate(5166-67-6)1HNMR
Ethyl 1-methylnipecotate(5166-67-6)13CNMR
Ethyl 1-methylnipecotate(5166-67-6)IR1
Ethyl 1-methylnipecotate(5166-67-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethyl 1-methylnipecotate, 98+%(5166-67-6)
[Sigma Aldrich]

5166-67-6(sigmaaldrich)
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