| Identification | More | [Name]
4-BROMOBENZOPHENONE | [CAS]
90-90-4 | [Synonyms]
4-BROMOBENZOPHENONE
LABOTEST-BB LT00053402
P-BROMOBENZOPHENONE
(4-Bromophenyl)(phenyl)methanone
(4-bromophenyl)phenyl-methanon
4-bromo-benzophenon
4-bromophenylphenylketone
Benzophenone, 4-bromo-
p-benzoylbromobenzene
USAF do-3
4-Bromobenzophenone,98%
p-BROMOBENZOPHENONE pure
Phenyl-4-Bromophenyl Ketone
p-Bromodiphenyl Ketone | [EINECS(EC#)]
202-024-9 | [Molecular Formula]
C13H9BrO | [MDL Number]
MFCD00000103 | [Molecular Weight]
261.11 | [MOL File]
90-90-4.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO LIGHT BEIGE CRYSTALLINE POWDER | [Melting point ]
79-84 °C(lit.)
| [Boiling point ]
350 °C(lit.)
| [density ]
1.4245 (rough estimate) | [refractive index ]
1.5130 (estimate) | [Fp ]
350°C | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Crystalline Powder | [color ]
White to light beige | [Water Solubility ]
Insoluble in water but slightly soluble in other solvents such as ethanol, ether and benzene. | [BRN ]
1910182 | [InChIKey]
KEOLYBMGRQYQTN-UHFFFAOYSA-N | [CAS DataBase Reference]
90-90-4(CAS DataBase Reference) | [EPA Substance Registry System]
4-Bromobenzophenone (90-90-4) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [RTECS ]
DJ0350000
| [HS Code ]
29147000 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO LIGHT BEIGE CRYSTALLINE POWDER | [Uses]
4-Bromobenzophenone is used in analytical applications such as HPLC and GC. It is also used as a chemical reagent and pharmaceutical intermediate. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 31, p. 2708, 1966 DOI: 10.1021/jo01346a526
Tetrahedron Letters, 27, p. 929, 1986 DOI: 10.1016/S0040-4039(00)84140-4 | [Purification Methods]
Crystallise the phenone from EtOH. The 2,4-dinitrophenylhydrazone forms orange-red leaflets from dioxane/EtOH with m 207-209o. [Allen & Van Allan J Am Chem Soc 66 7 1944, Beilstein 7 H 422, 7 III 2079, 7 IV 1378.] |
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