o-Toluamid
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- CAS-Nr.
- 527-85-5
- Bezeichnung:
- o-Toluamid
- Englisch Name:
- O-TOLUAMIDE
- Synonyma:
- O-TOLUAMIDE;2-TOLUAMIDE;o-Tolylamide;o-Toluic amide;ORTHO-TOLUAMIDE;o-Toluene amide;2-methyl-benzamid;2-METHYLBENZAMIDE;o-Methylbenzamide;Formyl-o-toluidine
- CBNumber:
- CB1311529
- Summenformel:
- C8H9NO
- Molgewicht:
- 135.16
- MOL-Datei:
- 527-85-5.mol
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o-Toluamid Eigenschaften
- Schmelzpunkt:
- 141-142 °C (lit.)
- Siedepunkt:
- 248.86°C (rough estimate)
- Dichte
- 1.086
- Brechungsindex
- 1.5589 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- Löslichkeit
- alcohol: very soluble(lit.)
- pka
- 16.01±0.50(Predicted)
- Merck
- 13,9606
- CAS Datenbank
- 527-85-5
- EPA chemische Informationen
- o-Toluamide (527-85-5)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Kennzeichnung gefährlicher |
Xn |
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| R-Sätze: |
22 |
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| WGK Germany |
3 |
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| HS Code |
2924297099 |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P270, P301+P312, P330, P501 |
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| Sicherheit |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
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o-Toluamid Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
2-Methylbenzamide (
o-Toluamide) has been used in total synthesis of phenolic protoberberine alkaloid, cerasonine.
Allgemeine Beschreibung
White powder.
Air & Water Reaktionen
Insoluble in water.
Reaktivität anzeigen
O-TOLUAMIDE is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Health Hazard
ACUTE/CHRONIC HAZARDS: O-TOLUAMIDE may react violently if exposed to open flame; it should be isolated from all sources of ignition.
Brandgefahr
Flash point data for O-TOLUAMIDE are not available, however O-TOLUAMIDE is probably combustible.
läuterung methode
Crystallise o-toluamide from hot water (10mL/g) and dry in air. [Noller Org Synth Coll Vol II 586 1943, Beilstein 9 H 465, 9 II 319, 9 III 2304.]
o-Toluamid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
o-Toluamid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 73)Lieferanten
527-85-5(o-Toluamid)Verwandte Suche:
Phenanthridin-6(5H)-on
N-Bromphthalimid
N-Hydroxyphthalimid
Benzol-1,2:4,5-tetracarboxydiimid
4-Nitrophthalimid
3-Iminoisoindolinon
N-Aminophthalimid
3,4,5,6-Tetrachlorphthalimid
Phthalimid
3,4,5,6-Tetrabromphthalimid
Ethyl-1,3-dihydro-1,3-dioxo-2H-isoindol-2-carboxylat
N-(Prop-2-ynyloxy)phthalimid
N-Kaliumphthalimid
N-(2,3-Epoxypropyl)phthalimid
Procarbazin
m-(Trifluormethyl)benzamid
p-Toluamid
N-(4-Amino-o-tolyl)-4-chlorphthalimid
- 2-METHYLBENZAMIDE
- 2-TOLUAMIDE
- 2-methyl-benzamid
- Formyl-o-toluidine
- o-Methylbenzamide
- o-Toluic amide
- o-Tolylamide
- Benzamide, 2-methyl- (9CI)
- TIMTEC-BB SBB007860
- O-TOLUAMIDE
- ORTHO-TOLUAMIDE
- o-Toluene amide
- BenzaMide, 2-Methyl-
- 527-85-5
- CH3C6H4CONH2
- Amides
- Building Blocks
- Carbonyl Compounds
- Organic Building Blocks
- Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
- AMIDE
