(8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid
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- CAS-Nr.
- 69257-04-1
- Bezeichnung:
- (8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid
- Englisch Name:
- N-Benzylcinchonidinium chloride
- Synonyma:
- BCDC;SF120116;-hydroxy(quinolin-4-yl);N-benzyl chlorideCinchonidine;N-BENZYLCINCHONIDINIUM CHLORIDE;N-Benzylcinchoninium chloride ,99%;N-Benzylcinchonidinium chloride ,99%;N-Benzylcinchonidinium Chloride N-Benzylcinchonidinium chloride, BCDC;N-BENZYLCINCHONIDINIUM CHLORIDE HYDRATE
- CBNumber:
- CB3757952
- Summenformel:
- C26H29ClN2O
- Molgewicht:
- 420.97
- MOL-Datei:
- 69257-04-1.mol
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(8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid Eigenschaften
- Schmelzpunkt:
- 210 °C (dec.)(lit.)
- alpha
- -188 º (c=0.4% in H2O)
- Brechungsindex
- -184 ° (C=1, H2O)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- Löslichkeit
- soluble in Methanol
- Aggregatzustand
- powder to crystal
- Farbe
- White to Light yellow to Light orange
- Optische Aktivität
- [α]20/D 180°, c = 1.3 in H2O
- BRN
- 5421832
- InChIKey
- FCHYSBWCOKEPNQ-WOIURNJWSA-M
(8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
white to light yellow crystal powde
läuterung methode
Dissolve the chloride in the minimum volume of H2O and add absolute Me2CO. Filter it off and dry it in a vacuum. It can also be recrystallised from hot EtOH or EtOH/Et2O. (A good chiral phase transfer catalyst-see above) [Colonna et al. J Chem Soc, Perkin Trans 1 547 1981, Imperali & Fisher J Org Chem 57 757 1992]. [Beilstein 23 H 446.] See cinchonidine below.
(8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 111)Lieferanten
69257-04-1((8α,9R)-1-Benzyl-9-hydroxycinchonaniumchlorid)Verwandte Suche:
- Cinchonanium, 9-hydroxy-1-(phenylmethyl)-, chloride, (8.alpha.,9R)-
- (8alpha,9R)-1-benzyl-9-hydroxycinchonanium chloride
- (8S,9R)-(-)-BENZYLCINCHONIDINIUM CHLORID E, 98%
- N-BENZYLCINCHONIDINIUM CHLORIDE HYDRATE
- N-Benzylcinchonidinium Chloride [Chiral Phase-Transfer Catalyst]
- N-Benzylcinchonidinium chloride, BCDC
- N-Benzylcinchoninium chloride ,99%
- (8S,9R)-1-Benzyl-9-hydroxycinchonan-1-ium·chloride
- (αR,1S,4α)-α-(4-Quinolyl)-1β-benzyl-5β-vinyl-1-azoniabicyclo[2.2.2]octane-2α-methanol·chloride
- N-Benzylcinchonidinium chloride ,99%
- N-benzyl chlorideCinchonidine
- (8S,9R)-(-)-N-Benzylcinchonidinium chloride 98%
- N-Benzylcinchonidinium Chloride
- -hydroxy(quinolin-4-yl)
- N-BENZYLCINCHONIDINIUM CHLORIDE
- (8a,9r)-1-benzyl-9-hydroxycinchonanium chloride
- (8S,9R)-(-)-N-BENZYLCINCHONIDINIUM CHLORIDE
- BCDC
- [5-ethenyl-1-(phenylmethyl)-1-azoniabicyclo[2.2.2]octan-2-yl]-(4-quinolinyl)methanol
- (R)-[(1S,2S,4S,5R)-1-benzyl-5-vinyl-quinuclidin-1-ium-2-yl]-(4-quinolyl)methanol
- (2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(quinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride
- SF120116
- N-Benzylcinchonidinium Chloride [Chiral Phase-Transfer Catalyst]>
- N-Benzylcinchonidinium chloride ISO 9001：2015 REACH
- (R)-[(2S,4S,5R)-1-Benzyl-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-quinolin-4-ylmethanol Chloride
- 69257-04-1
- C26H29N2OCl
- C26H29ClN2OxH2O
- Quinoline Alkaloids
- Quinolines
- Asymmetric Synthesis
- Ammonium Chlorides (Quaternary)
- Quinolinecarboxylic Acids, etc.
- Chiral Phase-Transfer Catalysts
- Quaternary Ammonium Compounds
- Alkaloids
- Phase Transfer Reaction
- Privileged Ligands
- Cinchona Alkaloids
- Chiral Catalysts, Ligands, and Reagents
- Quinoline Alkaloids
- Alkaloids
- Ammonium Chlorides (Quaternary)
- Asymmetric Synthesis
- Biochemistry
- Quaternary Ammonium Compounds
- Quinolinecarboxylic Acids, etc.
- Quinolines
- Synthetic Organic Chemistry
- chiral
- Chiral Phase-Transfer Catalysts
