ChemicalBook >> CAS DataBase List >>tert-Butoxy bis(dimethylamino)methane

tert-Butoxy bis(dimethylamino)methane

tert-Butoxy bis(dimethylamino)methane structure

CAS No.: 5815-08-7

Chemical Name:: tert-Butoxy bis(dimethylamino)methane

Synonyms: 1-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine;TERT-BUTOXYBIS(DIMETHYLAMINO)METHANE;[(tert-butoxy)(diMethylaMino)Methyl]diMethylaMine;T-BUTOXYBIS(DIMETHYLAMINO)METHANE;BUTOXYBIS(DIMETHYLAMINO)METHANE;5815/8/7;Bredereck'sreagen;BREDERECKS REAGENT;BREDERECK'S REAGENT;Bredereck's reagent

CBNumber:: CB0122973

Molecular Formula:: C9H22N2O

Molecular Weight:: 174.28

MDL Number:: MFCD00042858

MOL File:: 5815-08-7.mol

MSDS File:: SDS

Last updated:2024-08-22 11:38:30

Request For Quotation

tert-Butoxy bis(dimethylamino)methane Properties

Boiling point	50-55 °C/15 mmHg (lit.)
Density	0.844 g/mL at 25 °C (lit.)
refractive index	n20/D 1.422(lit.)
Flash point	106 °F
storage temp.	Sealed in dry,Store in freezer, under -20°C
solubility	Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly)
pka	5.46±0.38(Predicted)
form	Liquid
color	Clear pale yellow
Specific Gravity	0.844
BRN	1901973
Stability	Hygroscopic
InChI	InChI=1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3
InChIKey	HXRAMSFGUAOAJR-UHFFFAOYSA-N
SMILES	C(OC(C)(C)C)(N(C)C)N(C)C
CAS DataBase Reference	5815-08-7(CAS DataBase Reference)
FDA UNII	JEJ0U558F7

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07

Signal word

Warning

Hazard statements

H226-H315-H319-H335

Precautionary statements

P210-P302+P352-P305+P351+P338

Hazard Codes

Xi,F

Risk Statements

10-36/37/38

Safety Statements

RIDADR

UN 1993 3/PG 3

WGK Germany

HazardClass

PackingGroup

III

HS Code

29221990

NFPA 704

	2
2		0

tert-Butoxy bis(dimethylamino)methane price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	20425	tert-Butoxy bis(dimethylamino)methane technical	5815-08-7	10ML	$304	2024-03-01	Buy
Sigma-Aldrich	20425	tert-Butoxy bis(dimethylamino)methane technical	5815-08-7	50ML	$1350	2024-03-01	Buy
Alfa Aesar	H27861	tert-Butoxybis(dimethylamino)methane, tech. 90%	5815-08-7	1g	$43.65	2024-03-01	Buy
Alfa Aesar	H27861	tert-Butoxybis(dimethylamino)methane, tech. 90%	5815-08-7	5g	$114.65	2024-03-01	Buy
Sigma-Aldrich	384216	tert-Butoxy bis(dimethylamino)methane	5815-08-7	1g	$31.5	2024-03-01	Buy

Product number	Packaging	Price	Buy
20425	10ML	$304	Buy
20425	50ML	$1350	Buy
H27861	1g	$43.65	Buy
H27861	5g	$114.65	Buy
384216	1g	$31.5	Buy

tert-Butoxy bis(dimethylamino)methane Chemical Properties,Uses,Production

Description

Bredereck's reagent, chemically known as tert-Butoxy bis(dimethylamino)methane, is a versatile reagent. It can be used for a-methylation, a-methylenation, and a-amidation of multiple carbonyl systems or compounds with active CH groups. The advantage is the in situ generation of strongly basic alkanes (t-BuO-) and the generation of the corresponding iminium ions by thermal decomposition. After the Mannich reaction of the carbonyl substrate with the in situ generated iminium ion, the dimethylamine is eliminated from the adduct B- in the final step to give the condensation product, which can be converted into various types of compounds.

Chemical Properties

Clear pale yellow liquid

Uses

Reactant for:

Preparation of pyrroloquinazolines as photochemotherapeutic agents
Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition
Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction
Aminomethylenation reactions

Uses

Mild enamination reagent; catalyst in ring-opening polymerization reactions.

Uses

Reactant for:• ;Preparation of pyrroloquinazolines as photochemotherapeutic agents1• ;Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2• ;Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3• ;Aminomethylenation reactions4

tert-Butoxy bis(dimethylamino)methane synthesis

Synthesis of tert-Butoxy bis(dimethylamino)methane from Potassium tert-butoxide and [(dimethylamino)methylene]dimethylammonium methyl sulphate

tert-Butoxy bis(dimethylamino)methane Preparation Products And Raw materials

Raw materials

Preparation Products

5-METHOXY-1H-PYRROLO[3,2-B]PYRIDINE Cyclohexaneacetic acid, 4-[4-[(1Z)-1-cyano-2-(diMethylaMino)ethenyl]phenyl]-, ethyl ester, trans- 2-Propen-1-one, 1-cyclohexyl-3-(dimethylamino)-, (E)- (8CI) 3-(dimethylamino)-1,2-diphenyl-2-propen-1-one EthenaMine, 2-(2-benzoxazolyl)-N,N-diMethyl-

5-[(DIMETHYLAMINO)METHYLENE]-3-PHENYL-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE 2-(2-BROMOPYRIDIN-4-YL)ACETONITRILE

1of2

tert-Butoxy bis(dimethylamino)methane Suppliers

Global( 169)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7193	58
CHANGZHOU HARVECHEM LTD	+86-0519-88784888 +8613906120163	inquiry@harvechem.com	China	263	58
Shijiazhuang Leon Chemicals Co.,Ltd	+8615203111882	leonchem@outlook.com	China	4	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29798	60
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10311	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39916	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49392	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9641	58

Supplier	Advantage
Shanghai UCHEM Inc.	58
CHANGZHOU HARVECHEM LTD	58
Shijiazhuang Leon Chemicals Co.,Ltd	58
Capot Chemical Co.,Ltd.	60
Nanjing ChemLin Chemical Industry Co., Ltd.	60
Shenzhen Nexconn Pharmatechs Ltd	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Antai Fine Chemical Technology Co.,Limited	58

View Lastest Price from tert-Butoxy bis(dimethylamino)methane manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-09-12	Bredereck’s Reagent 5815-08-7	US $10.00-50.00 / kg	1kg	>90%	20 tons	Shijiazhuang Leon Chemicals Co.,Ltd
2024-09-12	Bredereck's reagent 5815-08-7	US $11.00-190.00 / g	25g	0.90	200kg	Shanghai UCHEM Inc.
2024-05-11	polyamines	US $1060.00 / T	1T	98%	20T	Yujiang Chemical (Shandong) Co.,Ltd.

Bredereck’s Reagent
5815-08-7
US $10.00-50.00 / kg
>90%
Shijiazhuang Leon Chemicals Co.,Ltd

Bredereck's reagent
5815-08-7
US $11.00-190.00 / g
0.90
Shanghai UCHEM Inc.

polyamines
US $1060.00 / T
98%
Yujiang Chemical (Shandong) Co.,Ltd.

tert-Butoxy bis(dimethylamino)methane Spectrum

BREDERECK'S REAGENT(5815-08-7)¹HNMR BREDERECK'S REAGENT(5815-08-7)Raman BREDERECK'S REAGENT(5815-08-7)FT-IR

5815-08-7(tert-Butoxy bis(dimethylamino)methane)Related Search:

TERT-BUTYL 4-(2-HYDROXYETHYL)PIPERAZINE-1-CARBOXYLATE tert-Butyldimethylsilyl chloride TERT-BUTYL VINYL ETHER Poly(vinyl alcohol) Selenium dioxide

Trisodium citrate dihydrate 2,6-DIMETHYL-4-NITROSOPHENOL BREDERECK'S REAGENT METHOXY-BIS(DIMETHYLAMINO)METHANE

1of2

tert-Butoxy bis(dimethylamino)methane technical BREDERECKS REAGENT BREDERECK'S REAGENT tert-Butoxybis(dimethylamino)methane, 85+% Bis(dimethylamino)(tert-butoxy)methane N,N,N',N'-Tetramethyl(tert-butoxy)methanediamine N,N,N',N'-Tetramethyl-α-tert-butoxymethanediamine α-(1,1-Dimethylethoxy)-N,N,N',N'-tetramethylmethanediamine α-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine Tert-butoxy-bis(dimethylamine)methane Bredereck’s reagent, Bis(dimethylamino)(tert-butoxy)methane tert-Butoxybis(diMethylaMino)Methane 5GR Methanediamine, 1-(1,1-dimethylethoxy)-N,N,N,N-tetramethyl- TERT-BUTOXY BIS(DIMETHYLAMINO)METHANE (BREDERECKS REAGENT) tert-Butoxybis(dimethylamino)methane, tech. 1-(tert-Butoxy)-N,N,N',N'-tetramethylmethanediamine 90% Methanediamine,1-tert-butoxy-N,N,N',N'-tetramethyl- 5815/8/7 N,N,N',N'-tetramethyl-1-[(2-methylpropan-2-yl)oxy]methanediamine BREDERECK REAGENT (MIXTURE OF TERT-BUTOXY BIS(DIMETHYLAMINO)METHANE, TRIS(DIMETHYLAMINO)METHANE AND N,N-DIMETHYLFORMAMIDE DI-TERT-BUTYL ACETAL) tert-Butoxy bis(dimethylamino)methane, 90%, for synthesis tert-Butoxy bis(dimethyL Bredereck'sreagen BREDERECK'S REAGENT ISO 9001：2015 REACH 1-(1,1-Dimethylethoxy)-N,N,N',N'-tetramethyl-methanediamine (contains Tris(dimethylamino) Methane and N,N- Dimethylformamide Di-tert-butyl Acetal) (Technical Grade) T-BUTOXYBIS(DIMETHYLAMINO)METHANE TERT-BUTOXYBIS(DIMETHYLAMINO)METHANE BUTOXYBIS(DIMETHYLAMINO)METHANE [(tert-butoxy)(diMethylaMino)Methyl]diMethylaMine 1-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine Bredereck's reagent Methanediamine,1-tert-butoxy-N,N,N',N'-tetramethyl- 1-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine 5815-08-7 5815-8-7 C9H22N2O CH33COCHNCH322 Building Blocks Nitrogen Compounds Organic Building Blocks Polyamines Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Polyamines Elisa Kit-plant ELISA Kit